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DOI | 10.1039/c9gc00267g |
Towards sustainable elastomers from CO2: life cycle assessment of carbon capture and utilization for rubbers | |
Meys, Raoul1; Kaetelhoen, Arne1; Bardow, Andre1,2 | |
发表日期 | 2019 |
ISSN | 1463-9262 |
EISSN | 1463-9270 |
卷号 | 21期号:12页码:3334-3342 |
英文摘要 | Elastomers have been recently proposed to integrate CO2 as carbon feedstock. These elastomers are produced by reacting carbon dioxide with propylene oxide and maleic anhydride. The resulting cross-linkable polyether carbonate polyols can be combined with isocyanates to form a novel class of polymers: CO2-based rubbers. These CO2-based rubbers are able to substitute conventional rubbers in synthetic elastomer products, such as sealants or flexible tubes. In this work, we present the first Life Cycle Assessment for CO2-based rubbers. To compare CO2-based and conventional rubbers our assessment considers all relevant life cycle stages from cradle-to-grave. The production system of CO2-based rubbers encompasses a nearby ammonia plant as a CO2 source, the conversion of CO2 to polyols, the reaction of polyols with isocyanates and finally, the incineration of CO2-based rubbers. Our analysis shows that CO2-based rubbers containing approx. 20% wt. CO2 have a global warming impact of 4.93 kg CO2-eq. Thus, CO2-based rubbers are no carbon sink. However, CO2-based rubbers reduce global warming impact by up to 34% if they substitute, for example, hydrogenated nitrile butadiene rubber on an equal mass basis. Fossil resource depletion is reduced by up to 33%. In contrast, other impact categories like ionizing radiation are increased by the utilization of CO2-based rubbers in some cases. Thus, our study indicates that CO2-based rubbers provide a promising pathway to reduce global warming impact and fossil resource depletion. However, it is likely that some other environmental impact categories such as ionizing radiation and freshwater eutrophication are increased. |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
来源期刊 | GREEN CHEMISTRY
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/99254 |
作者单位 | 1.Rhein Westfal TH Aachen, Inst Tech Thermodynam, Schinkelstr 8, D-52062 Aachen, Germany; 2.Forschungszentrum Julich GmbH, Inst Energy & Climate Res Energy Syst Engn IEK 10, Julich, Germany |
推荐引用方式 GB/T 7714 | Meys, Raoul,Kaetelhoen, Arne,Bardow, Andre. Towards sustainable elastomers from CO2: life cycle assessment of carbon capture and utilization for rubbers[J],2019,21(12):3334-3342. |
APA | Meys, Raoul,Kaetelhoen, Arne,&Bardow, Andre.(2019).Towards sustainable elastomers from CO2: life cycle assessment of carbon capture and utilization for rubbers.GREEN CHEMISTRY,21(12),3334-3342. |
MLA | Meys, Raoul,et al."Towards sustainable elastomers from CO2: life cycle assessment of carbon capture and utilization for rubbers".GREEN CHEMISTRY 21.12(2019):3334-3342. |
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