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DOI	10.1016/j.cplett.2018.10.027
	Reaction rate constants with OH radicals at 253-328 K and atmospheric implications for (CF3)(2)CHOCxH(2x (+1)) (x=1, 2, 3)
	Li, Wei 1,2; Qin, Sheng 2; Zhang, Qiyan 2; Guo, Zhikai 2; Zhang, Xiaoling 1
发表日期	2019
ISSN	0009-2614
EISSN	1873-4448
卷号	714 页码:125-130
英文摘要	Rate constants at 253-328 K for reactions of OH radicals with (CF3)(2)CHOCH3 (k6), (CF3)(2)CHOCH2CH3 (k7), and (CF3)(2)CHOCH2CH2CH3 (k8) were studied using a relative rate method. Data on k6, k7, and k8 (2.13 x 10(-13), 1.07 x 10(-12), and 1.92 x 10(-12) cm(3) molecule(-1) s(-1), respectively) were obtained at 298 K. The corresponding radiative efficiencies (0.103, 0.034, and 0.021 W m(-2) ppb(-1)) were calculated from infrared absorption spectra measured at room temperature. Global warming potential (GWP(100)) was estimated to be 5, < 1, and < 1, respectively, and the photochemical ozone creation potential in all cases was < 10.
WOS研究方向	Chemistry ; Physics
来源期刊	CHEMICAL PHYSICS LETTERS
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/92136
作者单位	1.Beijing Inst Technol, Sch Chem & Chem Engn, 5 South Zhonguancun St, Beijing 100081, Peoples R China; 2.Zhejiang Res Inst Chem Ind, State Key Lab Fluorine Greenhouse Gases Replaceme, Hangzhou 310023, Zhejiang, Peoples R China
推荐引用方式 GB/T 7714	Li, Wei,Qin, Sheng,Zhang, Qiyan,et al. Reaction rate constants with OH radicals at 253-328 K and atmospheric implications for (CF3)(2)CHOCxH(2x (+1)) (x=1, 2, 3)[J],2019,714:125-130.
APA	Li, Wei,Qin, Sheng,Zhang, Qiyan,Guo, Zhikai,&Zhang, Xiaoling.(2019).Reaction rate constants with OH radicals at 253-328 K and atmospheric implications for (CF3)(2)CHOCxH(2x (+1)) (x=1, 2, 3).CHEMICAL PHYSICS LETTERS,714,125-130.
MLA	Li, Wei,et al."Reaction rate constants with OH radicals at 253-328 K and atmospheric implications for (CF3)(2)CHOCxH(2x (+1)) (x=1, 2, 3)".CHEMICAL PHYSICS LETTERS 714(2019):125-130.