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DOI10.1002/chem.201805264
On the Theory of Electrolytic Dissociation, the Greenhouse Effect, and Activation Energy in (Electro)Catalysis: A Tribute to Svante Augustus Arrhenius
Masa, Justus; Barwe, Stefan; Andronescu, Corina; Schuhmann, Wolfgang
发表日期2019
ISSN0947-6539
EISSN1521-3765
卷号25期号:1页码:158-166
英文摘要

There are powerful lessons to take from Svante August Arrhenius' journey leading to a Nobel laureate as there are from his tremendous contributions to chemistry and science in general, including climate science, immunochemistry and cosmology. The theory of electrolytic dissociation for which Arrhenius received the 1903 Nobel Prize in Chemistry has had a profound impact on our understanding of the chemistry of solutions, chemical reactivity, mechanisms underlying chemical transformations as well as physiological processes. As a tribute to Arrhenius, we present a brief historical perspective and present status of the theory of electrolytic dissociation, its relevance and role to the development of electrochemistry, as well as some perspectives on the possible role of the theory to future advancements in electroanalysis, electrocatalysis and electrochemical energy storage. The review briefly highlights Arrhenius' contribution to climate science owing to his studies on the potential effects of increased anthropogenic CO2 emissions on the global climate. These studies were far ahead of their time and revealed a daunting global dilemma, global warming, that we are faced with today. Efforts to abate or reverse CO2 accumulation constitute one of the most pressing scientific problems of our time, "man's urgent strive to save self from the adverse effects of his self-orchestrated change on the climate". Finally, we review the application of the Arrhenius equation that correlates reaction rate constants (k) and temperature (T); k=Ae(-Ea/RT), in determining reaction barriers in catalysis with a particular focus on recent modifications of the equation to account for reactions exhibiting non-linear Arrhenius behavior with concave curvature due to prevalence of quantum mechanical tunneling, as well as infrequent convexity of Arrhenius plots due to decrease of the microcanonical rate coefficient with energy as observed for some enzyme catalyzed reactions.


WOS研究方向Chemistry
来源期刊CHEMISTRY-A EUROPEAN JOURNAL
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/91864
作者单位Ruhr Univ Bochum, Analyt Chem, CES, Fac Chem & Biochem, Univ Str 150, D-44780 Bochum, Germany
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GB/T 7714
Masa, Justus,Barwe, Stefan,Andronescu, Corina,et al. On the Theory of Electrolytic Dissociation, the Greenhouse Effect, and Activation Energy in (Electro)Catalysis: A Tribute to Svante Augustus Arrhenius[J],2019,25(1):158-166.
APA Masa, Justus,Barwe, Stefan,Andronescu, Corina,&Schuhmann, Wolfgang.(2019).On the Theory of Electrolytic Dissociation, the Greenhouse Effect, and Activation Energy in (Electro)Catalysis: A Tribute to Svante Augustus Arrhenius.CHEMISTRY-A EUROPEAN JOURNAL,25(1),158-166.
MLA Masa, Justus,et al."On the Theory of Electrolytic Dissociation, the Greenhouse Effect, and Activation Energy in (Electro)Catalysis: A Tribute to Svante Augustus Arrhenius".CHEMISTRY-A EUROPEAN JOURNAL 25.1(2019):158-166.
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