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DOI10.1021/acs.analchem.6b05066
Simple Method for High-Sensitivity Determination of Cosmogenic S-35 in Snow and Water Samples Collected from Remote Regions
Lin, Mang1; Wang, Kun1,2,4; Kang, Shichang2,3,4; Thiemens, Mark H.1
发表日期2017
ISSN0003-2700
EISSN1520-6882
卷号89期号:7页码:4116-4123
英文摘要

Cosmogenic S-35 is useful in understanding a wide variety of chemical and physical processes in the atmosphere, the hydrosphere, and the cryosphere. The 87.4-day half-life and the ubiquity of sulfur in natural environments renders it an ideal tracer of many phenomena. Measurements of S-35 in snow and water samples are scarce as existing analytical methods require a large volume of sample (>20 L) due to their high analytical activity background and low counting efficiency. Here, we present a new set of snow/water sample collecting and handling procedures for high-sensitivity determination of cosmogenic S-35 using a low-level liquid scintillation spectrometer. Laboratory experiments using diluted S-35 standards (with activities of <5 disintegrations per minute) showed a S-35 recovery percentage of similar to 95%, demonstrating a relatively small deviation from the true value. Using this method, we successfully measured S-35 in similar to 1 L of fresh snow sample collected from a glacier on the Tibetan Plateau to be 47 +/- 7 mBq/L. On the basis of S-35 activities in 9 natural samples measured in this study, a first proof-of-concept approximation for age determinations and source attributions was presented. This new method will provide a powerful tool in studying S-35 in small volumes of snow and water samples, especially those from remote but climatically important regions such as the polar regions and the Tibetan Plateau and Himalayas. The measurements are particularly important as the radioactive sulfur provides an actual clock of glacial melting processes. With the growing rate of glacial loss, the need for measurements from remote locations becomes all the more important.


语种英语
WOS研究方向Chemistry
来源期刊ANALYTICAL CHEMISTRY
来源机构中国科学院西北资源环境生态研究院
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/89631
作者单位1.Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA;;
2.Chinese Acad Sci, Northwest Inst Ecoenvironm & Resources, State Key Lab Cryosphere Sci, Lanzhou 730000, Peoples R China;;
3.CAS Ctr Excellence Tibetan Plateau Earth Sci, Beijing 100101, Peoples R China;;
4.Univ CAS, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Lin, Mang,Wang, Kun,Kang, Shichang,et al. Simple Method for High-Sensitivity Determination of Cosmogenic S-35 in Snow and Water Samples Collected from Remote Regions[J]. 中国科学院西北资源环境生态研究院,2017,89(7):4116-4123.
APA Lin, Mang,Wang, Kun,Kang, Shichang,&Thiemens, Mark H..(2017).Simple Method for High-Sensitivity Determination of Cosmogenic S-35 in Snow and Water Samples Collected from Remote Regions.ANALYTICAL CHEMISTRY,89(7),4116-4123.
MLA Lin, Mang,et al."Simple Method for High-Sensitivity Determination of Cosmogenic S-35 in Snow and Water Samples Collected from Remote Regions".ANALYTICAL CHEMISTRY 89.7(2017):4116-4123.
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