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RUI: Reactive Uptake and Heterogeneous Chemistry of Biogenic VOCs on Mineral Aerosol | |
项目编号 | 1400556 |
Ryan Hinrichs | |
项目主持机构 | Drew University |
开始日期 | 2014-07-15 |
结束日期 | 2017-06-30 |
英文摘要 | Design of Efficient Molecular Electrocatalysts for Water and Carbon Dioxide Reduction Using Predictive Models of Thermodynamic Properties Dr. Jenny Y. YangDepartment of ChemistryUniversity of California, IrvineIrvine, California, 92697-2025 The proposed research focuses on developing catalysts that can perform the reduction of water to hydrogen, and carbon dioxide to formate using an electrochemical potential. Both products can be used directly as an energy carrier in fuel cells, or to generate more saturated chemical fuels. Formate is also an intermediate in the sequential reduction of CO2 to methanol, another useful chemical fuel. Molecular inorganic complexes provide an opportunity to use electronic and steric ligand effects to optimize the critical thermodynamic parameters in catalytic intermediates. These parameters will be systematically measured for a series of abundant metal complexes to form predictive models for metal and ligand electronic effects. This principle will be applied to the design of aqueous homogeneous catalysts for the reduction of H2O and CO2 optimized to function at specific pH ranges. The thermodynamic properties measured will also be broadly applicable to other reductive reactions for the production and utilization of chemical fuels. |
学科分类 | 14 - 医学科学;08 - 地球科学;0805 - 大气科学 |
资助机构 | US-NSF |
项目经费 | 285568 |
项目类型 | Standard Grant |
国家 | US |
语种 | 英语 |
文献类型 | 项目 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/74560 |
推荐引用方式 GB/T 7714 | Ryan Hinrichs.RUI: Reactive Uptake and Heterogeneous Chemistry of Biogenic VOCs on Mineral Aerosol.2014. |
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