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DOI10.5194/acp-16-1245-2016
Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols
Riedel, T. P.1,3; Lin, Y. -H.1,4; Zhang, Z.1; Chu, K.1; Thornton, J. A.2; Vizuete, W.1; Gold, A.1; Surratt, J. D.1
发表日期2016
ISSN1680-7316
卷号16期号:3页码:1245-1254
英文摘要

Isomeric epoxydiols from isoprene photooxidation (IEPOX) have been shown to produce substantial amounts of secondary organic aerosol (SOA) mass and are therefore considered a major isoprene-derived SOA precursor. Heterogeneous reactions of IEPOX on atmospheric aerosols form various aerosol-phase components or "tracers" that contribute to the SOA mass burden. A limited number of the reaction rate constants for these acid-catalyzed aqueous-phase tracer formation reactions have been constrained through bulk laboratory measurements. We have designed a chemical box model with multiple experimental constraints to explicitly simulate gas-and aqueous-phase reactions during chamber experiments of SOA growth from IEPOX uptake onto acidic sulfate aerosol. The model is constrained by measurements of the IEPOX reactive uptake coefficient, IEPOX and aerosol chamber wall losses, chamber-measured aerosol mass and surface area concentrations, aerosol thermodynamic model calculations, and offline filter-based measurements of SOA tracers. By requiring the model output to match the SOA growth and offline filter measurements collected during the chamber experiments, we derive estimates of the tracer formation reaction rate constants that have not yet been measured or estimated for bulk solutions.


语种英语
WOS记录号WOS:000371284100003
来源期刊ATMOSPHERIC CHEMISTRY AND PHYSICS
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/61009
作者单位1.Univ N Carolina, Dept Environm Sci & Engn, Gillings Sch Global Publ Hlth, Chapel Hill, NC USA;
2.Univ Washington, Dept Atmospher Sci, Seattle, WA 98195 USA;
3.US EPA, Natl Exposure Res Lab, Res Triangle Pk, NC 27711 USA;
4.Univ Michigan, Michigan Soc Fellows, Dept Chem, Ann Arbor, MI 48109 USA
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GB/T 7714
Riedel, T. P.,Lin, Y. -H.,Zhang, Z.,et al. Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols[J]. 美国环保署,2016,16(3):1245-1254.
APA Riedel, T. P..,Lin, Y. -H..,Zhang, Z..,Chu, K..,Thornton, J. A..,...&Surratt, J. D..(2016).Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols.ATMOSPHERIC CHEMISTRY AND PHYSICS,16(3),1245-1254.
MLA Riedel, T. P.,et al."Constraining condensed-phase formation kinetics of secondary organic aerosol components from isoprene epoxydiols".ATMOSPHERIC CHEMISTRY AND PHYSICS 16.3(2016):1245-1254.
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