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DOI10.1038/s41598-018-20544-5
Reactive gaseous mercury is generated from chloralkali factories resulting in extreme concentrations of mercury in hair of workers
Elgazali, Abdelkarem A. S.1; Gajdosechova, Zuzana1; Abbas, Zaigham2; Lombi, Enzo3; Scheckel, Kirk G.3,4; Donner, Erica3; Fiedler, Heidelore5,6; Feldmann, Jorg1; Krupp, Eva M.1
发表日期2018-02-27
ISSN2045-2322
卷号8
英文摘要

Occupational exposure of chloralkali workers to highly concentrated mercury (Hg) vapour has been linked to an increased risk of renal dysfunction and behavioural changes. It is generally believed that these workers are exposed to elemental Hg, which is used in abundance during the production process however, the lack in analytical techniques that would allow for identification of gaseous Hg species poses a challenge, which needs to be addressed in order to reach a consensus. Here, we present the results from simulated exposure studies, which provide sound evidence of higher adsorption rate of HgCl2 than Hg-0 and its irreversible bonding on the surface of hair. We found that chloralkali workers were exposed to HgCl2, which accumulated in extremely high concentrations on the hair surface, more than 1,000 times higher than expected from unexposed subjects and was positively correlated with Hg levels in the finger- and toenails.


语种英语
WOS记录号WOS:000426151800008
来源期刊SCIENTIFIC REPORTS
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/60910
作者单位1.Univ Aberdeen, Trace Element Speciat Lab, Dept Chem, Aberdeen, Scotland;
2.Govt Pakistan Minist Climate Change, LG&RD Complex, Islamabad, Pakistan;
3.Univ South Australia, Future Ind Inst, Bldg X,Mawson Lakes Campus, Mawson Lakes, SA, Australia;
4.US Environm Protect Agcy, Natl Risk Management Res Lab, Cincinnati, OH 45224 USA;
5.United Nations Environm Programme, Chem Branch, DTIE, 11-13 Chemin Anemones, CH-1219 Chatelaine, Switzerland;
6.Univ Orebro, Sch Sci & Technol, MTM Res Ctr, SE-70182 Orebro, Sweden
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Elgazali, Abdelkarem A. S.,Gajdosechova, Zuzana,Abbas, Zaigham,et al. Reactive gaseous mercury is generated from chloralkali factories resulting in extreme concentrations of mercury in hair of workers[J]. 美国环保署,2018,8.
APA Elgazali, Abdelkarem A. S..,Gajdosechova, Zuzana.,Abbas, Zaigham.,Lombi, Enzo.,Scheckel, Kirk G..,...&Krupp, Eva M..(2018).Reactive gaseous mercury is generated from chloralkali factories resulting in extreme concentrations of mercury in hair of workers.SCIENTIFIC REPORTS,8.
MLA Elgazali, Abdelkarem A. S.,et al."Reactive gaseous mercury is generated from chloralkali factories resulting in extreme concentrations of mercury in hair of workers".SCIENTIFIC REPORTS 8(2018).
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