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DOI10.1021/acs.est.5b02957
Uranium Redistribution Due to Water Table Fluctuations in Sandy Wetland Mesocosms
Gilson, Emily R.1; Huang, Shan1; van Groos, Paul G. Koster1; Scheckel, Kirk G.2; Qafoku, Odeta3; Peacock, Aaron D.4; Kaplan, Daniel I.5; Jaffe, Peter R.1
发表日期2015-10-20
ISSN0013-936X
卷号49期号:20页码:12214-12222
英文摘要

To understand better the fate and stability of immobilized uranium (U) in wetland sediments, and how intermittent dry periods affect U stability, we dosed saturated sandy wetland mesocosms planted with Scirpus acutus with low levels of uranyl acetate for 4 months before imposing a short drying and rewetting period. Concentrations of U in mesocosm effluent increased after drying and rewetting, but the cumulative amount of U released following the dry period constituted less than 1% of the total U immobilized in the soil during the 4 months prior. This low level of remobilization suggests, and XANES analyses confirm, that microbial reduction was not the primary means of U immobilization, as the U immobilized in mesocosms was primarily U(VI) rather than U(IV). Drying followed by rewetting caused a redistribution of U downward in the soil profile and to root surfaces. Although the U on roots before drying was primarily associated with minerals, the U that relocated to the roots during drying and rewetting was bound diffusely. Results show that short periods of drought conditions in a sandy wetland, which expose reduced sediments to air, may impact U distribution without causing large releases of soil-bound U to surface waters.


语种英语
WOS记录号WOS:000363348700027
来源期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/60589
作者单位1.Princeton Univ, Princeton, NJ 08540 USA;
2.US EPA, Cincinnati, OH 45268 USA;
3.Pacific NW Natl Lab, Richland, WA 99352 USA;
4.Pace Analyt Energy Serv, Pittsburgh, PA 15238 USA;
5.Savannah River Natl Lab, Aiken, SC 29808 USA
推荐引用方式
GB/T 7714
Gilson, Emily R.,Huang, Shan,van Groos, Paul G. Koster,et al. Uranium Redistribution Due to Water Table Fluctuations in Sandy Wetland Mesocosms[J]. 美国环保署,2015,49(20):12214-12222.
APA Gilson, Emily R..,Huang, Shan.,van Groos, Paul G. Koster.,Scheckel, Kirk G..,Qafoku, Odeta.,...&Jaffe, Peter R..(2015).Uranium Redistribution Due to Water Table Fluctuations in Sandy Wetland Mesocosms.ENVIRONMENTAL SCIENCE & TECHNOLOGY,49(20),12214-12222.
MLA Gilson, Emily R.,et al."Uranium Redistribution Due to Water Table Fluctuations in Sandy Wetland Mesocosms".ENVIRONMENTAL SCIENCE & TECHNOLOGY 49.20(2015):12214-12222.
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