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DOI10.3997/1873-0604.2017049
Specific polarizability of sand-clay mixtures with varying ethanol concentration
Sharma, Sundeep1; Slater, Lee1; Ntarlagiannis, Dimitrios1; Werkema, Dale2; Szabo, Zoltan3
发表日期2017-12-01
ISSN1569-4445
卷号15期号:6页码:615-624
英文摘要

We utilise a concept of specific polarizability (c(s)), represented as the ratio of mineral-fluid interface polarization per pore-normalised surface area S-p, to demonstrate the influence of clay-organic interaction on complex conductivity measurements. Complex conductivity measurements were performed on kaolinite-and illite-sand mixtures as a function of varying ethanol (EtOH) concentration (10% and 20% v/v). The specific surface area of each clay type and Ottawa sand was determined by nitrogen-gas-adsorption Brunauer-Emmett-Teller method. We also calculated the porosity and saturation of each mixture based on weight loss of dried samples. Debye decomposition, a phenomenological model, was applied to the complex conductivity data to determine normalised chargeability (m(n)). Specific polarizability estimates from previous complex conductivity measurements for bentonite-sand mixtures were compared with our dataset. The c(s) for all sand-clay mixtures decreased as the EtOH concentration increased from 0% to 10% to 20% v/v. We observe similar c(s) responses to EtOH concentration for all sand-clay mixtures. Analysis of variance with a level of significance alpha = 0.05 suggests that the suppression in c(s) responses with increasing EtOH concentration was statistically significant for all sand-clay mixtures. On the other hand, real conductivity showed only 10% to 20% v/v changes with increasing EtOH concentration. The c(s) estimates reflect the sensitivity of complex conductivity measurements to alteration in surface chemistry at available surface adsorption sites for different clay types, likely resulting from ion exchange at the clay surface and associated with kinetic reactions in the electrical double layer of the clay-water-EtOH media. Our results indicate a much larger influence of specific surface area and ethanol concentration on clay-driven polarization relative to changes in clay mineralogy.


语种英语
WOS记录号WOS:000419112000007
来源期刊NEAR SURFACE GEOPHYSICS
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/59684
作者单位1.Rutgers Univ Newark, Dept Earth & Environm Sci, Newark, NJ 07102 USA;
2.US EPA, Environm Chem Branch, Exposure Methods & Measurement Div, Natl Exposure Res Lab,Off Res & Dev, Las Vegas, NV 89119 USA;
3.US Geol Survey, New Jersey Water Sci Ctr, Lawrenceville, NJ 08648 USA
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GB/T 7714
Sharma, Sundeep,Slater, Lee,Ntarlagiannis, Dimitrios,et al. Specific polarizability of sand-clay mixtures with varying ethanol concentration[J]. 美国环保署,2017,15(6):615-624.
APA Sharma, Sundeep,Slater, Lee,Ntarlagiannis, Dimitrios,Werkema, Dale,&Szabo, Zoltan.(2017).Specific polarizability of sand-clay mixtures with varying ethanol concentration.NEAR SURFACE GEOPHYSICS,15(6),615-624.
MLA Sharma, Sundeep,et al."Specific polarizability of sand-clay mixtures with varying ethanol concentration".NEAR SURFACE GEOPHYSICS 15.6(2017):615-624.
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