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DOI10.2134/jeq2013.01.0004
Investigation of Copper Sorption by Sugar Beet Processing Lime Waste
Ippolito, J. A.1; Strawn, D. G.2; Scheckel, K. G.3
发表日期2013-05-01
ISSN0047-2425
卷号42期号:3页码:919-924
英文摘要

In the western United States, sugar beet processing for sugar recovery generates a lime-based waste product (similar to 250,000 Mg yr(-1)) that has little liming value in the region's calcareous soils. This area has recently experienced an increase in dairy production, with dairies using copper (Cu)-based hoof baths to prevent hoof diseases. A concern exists regarding soil Cu accumulation because spent hoof baths may be disposed of in waste ponds, with pond waters being used for irrigation. The objective of this preliminary study was to evaluate the ability of lime waste to sorb Cu. Lime waste was mixed with increasing Cu-containing solutions (up to 100,000 mg Cu kg(-1) lime waste) at various buffered pH values (pH 6, 7, 8, and 9) and shaken over various time periods (up to 30 d). Copper sorption phenomenon was quantified using sorption maximum fitting, and the sorption mechanism was investigated using X-ray absorption spectroscopy. Results showed that sorption onto lime waste increased with decreasing pH and that the maximum Cu sorption of similar to 45,000 mg kg(-1) occurred at pH 6. X-ray absorption spectroscopy indicated that Cu(OH)(2) was the probable species present, although the precipitate existed as small multinuclear precipitates on the surface of the lime waste. Such structures may be precursors for larger surface precipitates that develop over longer incubation times. Findings suggest that sugar beet processing lime waste can viably sorb Cu from liquid waste streams, and thus it may have the ability to remove Cu from spent hoof baths.


语种英语
WOS记录号WOS:000318213000033
来源期刊JOURNAL OF ENVIRONMENTAL QUALITY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/59360
作者单位1.USDA ARS, Northwest Irrigat & Soils Res Lab, Kimberly, ID 83341 USA;
2.Univ Idaho, Dept Plant Soil & Entomol Sci, Moscow, ID 83844 USA;
3.Natl Risk Management Res Lab, US Environm Protect Agcy, Cincinnati, OH 45224 USA
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GB/T 7714
Ippolito, J. A.,Strawn, D. G.,Scheckel, K. G.. Investigation of Copper Sorption by Sugar Beet Processing Lime Waste[J]. 美国环保署,2013,42(3):919-924.
APA Ippolito, J. A.,Strawn, D. G.,&Scheckel, K. G..(2013).Investigation of Copper Sorption by Sugar Beet Processing Lime Waste.JOURNAL OF ENVIRONMENTAL QUALITY,42(3),919-924.
MLA Ippolito, J. A.,et al."Investigation of Copper Sorption by Sugar Beet Processing Lime Waste".JOURNAL OF ENVIRONMENTAL QUALITY 42.3(2013):919-924.
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