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DOI | 10.1016/j.envpol.2018.04.086 |
Concentrations and variability of organophosphate esters, halogenated flame retardants, and polybrominated diphenyl ethers in indoor and outdoor air in Stockholm, Sweden | |
Wong, Fiona1,2; de Wit, Cynthia A.1; Newton, Seth R.1,3 | |
发表日期 | 2018-09-01 |
ISSN | 0269-7491 |
卷号 | 240页码:514-522 |
英文摘要 | We investigated the concentrations and temporal variability of organophospate esters (OPEs), halogenated flame retardants (HFRs) and polybrominated diphenyl ethers (PBDEs) in indoor and outdoor urban air in Stockholm, Sweden over one year (2014-2015) period. The median concentrations of the three target chemical groups (OPEs, HFRs, PBDEs) were 1-2 orders of magnitude higher in indoor air than outdoor urban air. OPEs were the most abundant target FRs with median concentrations in indoor (Sigma 10OPE = 340 000 pg/m(3)) and outdoor urban (Sigma 10OPEs = 3100 pg/m(3)) air, being 3 orders of magnitude greater than for HFRs in indoor (Sigma(15)HFRs = 120 pg/m(3)) and outdoor urban (Sigma(15)HFRs = 1.6 pg/m(3)) air. In indoor air, PBDE concentrations (Sigma 17PBDEs =33 pg/m(3)) were lower than for the HFRs, but in outdoor urban air, concentrations (Sigma 17PBDEs = 1.1 pg/m(3)) were similar to HFRs. The most abundant OPEs in both the indoor and outdoor urban air were tris(2-butoxyethyl)phosphate (TBOEP), tris(chloroisopropyl) phosphate (TCIPP), tris(2-chloroethyl)phosphate (TCEP), tri-n-butyl-phosphate (TnBP), triphenyl phosphate (TPhP) and tris(1,3-dichloroisopropyl)phosphate (TDCIPP). TCIPP in indoor air was found in the highest concentrations and showed the greatest temporal variability, which ranged from 85 000 to 1 900 000 pg/m(3) during the one-year sampling period. We speculate that activities in the building, e.g. floor cleaning, polishing, construction, introduction of new electronics and changes in ventilation rate could explain its variation. Some OPEs (TnBP, TCEP, TCIPP, TDCIPP and TPhP), HFRs/PBDEs (pentabromotoluene, 2, 3-dibromopropyl 2, 4, 6-tribromophenyl ether, hexabromobenzene, BDE-28, -47, and -99) in outdoor urban air showed seasonality, with increased concentrations during the warm period (p < 0.05, Pearson's r ranged from 0.45 to 0.91). The observed seasonality for OPEs was probably due to changes in primary emission, and those for the HFRs and PBDEs was likely due to re-volatilization from contaminated surfaces. (C) 2018 Published by Elsevier Ltd. |
语种 | 英语 |
WOS记录号 | WOS:000438322100055 |
来源期刊 | ENVIRONMENTAL POLLUTION
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来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/59127 |
作者单位 | 1.Stockholm Univ, Dept Environm Sci & Analyt Chem ACES, SE-10691 Stockholm, Sweden; 2.Environm & Climate Change Canada, Air Qual Proc Res Sect, 4905 Dufferin St, Toronto, ON M3H 5T4, Canada; 3.US EPA, Natl Exposure Res Lab, Res Triangle Pk, NC 27709 USA |
推荐引用方式 GB/T 7714 | Wong, Fiona,de Wit, Cynthia A.,Newton, Seth R.. Concentrations and variability of organophosphate esters, halogenated flame retardants, and polybrominated diphenyl ethers in indoor and outdoor air in Stockholm, Sweden[J]. 美国环保署,2018,240:514-522. |
APA | Wong, Fiona,de Wit, Cynthia A.,&Newton, Seth R..(2018).Concentrations and variability of organophosphate esters, halogenated flame retardants, and polybrominated diphenyl ethers in indoor and outdoor air in Stockholm, Sweden.ENVIRONMENTAL POLLUTION,240,514-522. |
MLA | Wong, Fiona,et al."Concentrations and variability of organophosphate esters, halogenated flame retardants, and polybrominated diphenyl ethers in indoor and outdoor air in Stockholm, Sweden".ENVIRONMENTAL POLLUTION 240(2018):514-522. |
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