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DOI10.1016/j.atmosenv.2014.05.041
Characterizing reduced sulfur compounds emissions from a swine concentrated animal feeding operation
Rumsey, Ian C.1; Aneja, Viney P.1; Lonneman, William A.2
发表日期2014-09-01
ISSN1352-2310
卷号94页码:458-466
英文摘要

Reduced sulfur compounds (RSCs) emissions from concentrated animal feeding operations (CAFOs) have become a potential environmental and human health concern, as a result of changes in livestock production methods. RSC emissions were determined from a swine CAFO in North Carolina. RSC measurements were made over a period of approximate to 1 week from both the barn and lagoon during each of the four seasonal periods from June 2007 to April 2008. During sampling, meteorological and other environmental parameters were measured continuously. Seasonal hydrogen sulfide (H2S) barn concentrations ranged from 72 to 631 ppb. Seasonal dimethyl sulfide (DMS; CH3SCH3) and dimethyl disulfide (DMDS; CH3S2CH3) concentrations were 2-3 orders of magnitude lower, ranging from 0.18 to 0.89 ppb and 0.47 to 1.02 ppb, respectively. The overall average barn emission rate was 3.3 g day(-1) AU(-1) (AU (animal unit) = 500 kg of live animal weight) for H2S, which was approximately two orders of magnitude higher than the DMS and DMDS overall average emissions rates, determined as 0.017 g day(-1) AU(-1) and 0.036 g day(-1) AU(-1), respectively. The overall average lagoon flux was 1.33 mu g m(-2) min(-1) for H2S, which was approximately an order of magnitude higher than the overall average DMS (0.12 mu g m(-2) min(-1)) and DMDS (0.09 mu g m(-2) min(-1)) lagoon fluxes. The overall average lagoon emission for H2S (0.038 g day(-1) AU(-1)) was also approximately an order of magnitude higher than the overall average DMS (0.0034 g day(-1) AU(-1)) and DMDS (0.0028 g day(-1) AU(-1)) emissions. H2S, DMS and DMDS have offensive odors and low odor thresholds. Over all four sampling seasons, 77% of 15 min averaged H2S barn concentrations were an order of magnitude above the average odor threshold. During these sampling periods, however, DMS and DMDS concentrations did not exceed their odor thresholds. The overall average barn and lagoon emissions from this study were used to help estimate barn, lagoon and total (barn + lagoon) RSC emissions from swine CAFOs in North Carolina. Total (barn + lagoon) H2S emissions from swine CAFOs in North Carolina were estimated to be 1.22*10(6) kg yr(-1). The barns had significantly higher H2S emissions than the lagoons, contributing approximate to 98% of total North Carolina H2S swine CAFO emissions. Total (barn + lagoon) emissions for DMS and DMDS were 1-2 orders of magnitude lower, with barns contributing approximate to 86% and approximate to 93% of total emissions, respectively. H2S swine CAFO emissions were estimated to contribute approximate to 18% of North Carolina H2S emissions. (C) 2014 Elsevier Ltd. All rights reserved.


英文关键词Reduced sulfur compounds;Hydrogen sulfide;CAFO emissions;Swine
语种英语
WOS记录号WOS:000340316300050
来源期刊ATMOSPHERIC ENVIRONMENT
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/58230
作者单位1.N Carolina State Univ, Dept Marine Earth & Atmospher Sci, Raleigh, NC 27695 USA;
2.US EPA, Sr Environm Employment Program, Res Triangle Pk, NC 27711 USA
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GB/T 7714
Rumsey, Ian C.,Aneja, Viney P.,Lonneman, William A.. Characterizing reduced sulfur compounds emissions from a swine concentrated animal feeding operation[J]. 美国环保署,2014,94:458-466.
APA Rumsey, Ian C.,Aneja, Viney P.,&Lonneman, William A..(2014).Characterizing reduced sulfur compounds emissions from a swine concentrated animal feeding operation.ATMOSPHERIC ENVIRONMENT,94,458-466.
MLA Rumsey, Ian C.,et al."Characterizing reduced sulfur compounds emissions from a swine concentrated animal feeding operation".ATMOSPHERIC ENVIRONMENT 94(2014):458-466.
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