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DOI10.1002/2017GL072602
The global nonmethane reactive organic carbon budget: A modeling perspective
Safieddine, Sarah A.1; Heald, Colette L.1; Henderson, Barron H.2
发表日期2017-04-28
ISSN0094-8276
卷号44期号:8页码:3897-3906
英文摘要

The cycling of reactive organic carbon (ROC) is central to tropospheric chemistry. We characterize the global tropospheric ROC budget as simulated with the GEOS-Chem model. We expand the standard simulation by including new emissions and gas-phase chemistry, an expansion of dry and wet removal, and a mass tracking of all ROC species to achieve carbon closure. The resulting global annual mean ROC burden is 16 Tg C, with sources from methane oxidation and direct emissions contributing 415 and 935 Tg C yr(-1). ROC is lost from the atmosphere via physical deposition (460 Tg C yr(-1)), and oxidation to CO/CO2 (875 Tg C yr(-1)). Ketones, alkanes, alkenes, and aromatic hydrocarbons dominate the ROC burden, whereas aldehydes and isoprene dominate the ROC global mean surface OH reactivity. Simulated OH reactivities are between 0.8-1 s(-1), 3-14 s(-1), and 12-34 s(-1) over selected regions in the remote ocean, continental midlatitudes, and the tropics, respectively, and are consistent with observational constraints.


英文关键词reactive organic carbon;OH reactivity
语种英语
WOS记录号WOS:000401847500053
来源期刊GEOPHYSICAL RESEARCH LETTERS
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/57859
作者单位1.MIT, Dept Civil & Environm Engn, 77 Massachusetts Ave, Cambridge, MA 02139 USA;
2.US EPA, Off Air Qual Planning & Stand, Res Triangle Pk, NC 27711 USA
推荐引用方式
GB/T 7714
Safieddine, Sarah A.,Heald, Colette L.,Henderson, Barron H.. The global nonmethane reactive organic carbon budget: A modeling perspective[J]. 美国环保署,2017,44(8):3897-3906.
APA Safieddine, Sarah A.,Heald, Colette L.,&Henderson, Barron H..(2017).The global nonmethane reactive organic carbon budget: A modeling perspective.GEOPHYSICAL RESEARCH LETTERS,44(8),3897-3906.
MLA Safieddine, Sarah A.,et al."The global nonmethane reactive organic carbon budget: A modeling perspective".GEOPHYSICAL RESEARCH LETTERS 44.8(2017):3897-3906.
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