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DOI10.1021/es304580r
Key Factors Controlling the Transport of Silver Nanoparticles in Porous Media
El Badawy, Amro M.1; Hassan, Ashraf Aly2; Scheckel, Kirk G.2; Suidan, Makram T.1; Tolaymat, Thabet M.2
发表日期2013-05-07
ISSN0013-936X
卷号47期号:9页码:4039-4045
英文摘要

The current study investigated the mobility of four silver nanoparticles (AgNPs) stabilized using different capping agents and represent the common stabilization mechanisms as well as surface charging scenarios in reactive and nonreactive porous media. The AgNPs were (1) uncoated H-2-AgNPs (electrostatically stabilized) and (2) citrate coated AgNPs (Citrate-AgNPs) (electrostatically stabilized), (3) polyvinylpyrrolidone coated AgNPs (PVP-AgNPs) (sterically stabilized), and (4) branched polyethyleneimine coated AgNPs (BPEI-AgNPs) (electrosterically stabilized). The porous media were (1) quartz sand (QS), (2) ferrihydrite-coated sand (FcS), and (3) kaolin coated sand (KcS). The H-2-AgNPs and Citrate-AgNPs were readily mobile in QS but significantly retained in FcS and KcS with more deposition achieved in the KcS media. The deposition of the H-2-AgNPs and Citrate-AgNPs followed the order of KcS > FcS > QS. The PVP-AgNPs breakthrough occurred more rapid as compared to the H-2-AgNPs and Citrate-AgNPs but the deposition of PVP-AgNPs followed the same order electrostatically stabilized AgNPs (KcS > FcS > QS). The BPEI-AgNPs were readily mobile regardless of the porous media reactivity. Physicochemical interactions were the dominant filtration mechanism in the majority of the investigated cases but straining played the major role in the deposition of the electrostatically stabilized H-2-AgNPs and Citrate-AgNPs in the KcS media. The results highlight the importance of both the stabilization mechanism and capping agent chemistry as key factors governing the transport of AgNPs in the environment.


语种英语
WOS记录号WOS:000318756000013
来源期刊ENVIRONMENTAL SCIENCE & TECHNOLOGY
来源机构美国环保署
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/57440
作者单位1.Univ Cincinnati, Dept Environm Engn, Cincinnati, OH 45221 USA;
2.US EPA, Off Res & Dev, Cincinnati, OH 45224 USA
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GB/T 7714
El Badawy, Amro M.,Hassan, Ashraf Aly,Scheckel, Kirk G.,et al. Key Factors Controlling the Transport of Silver Nanoparticles in Porous Media[J]. 美国环保署,2013,47(9):4039-4045.
APA El Badawy, Amro M.,Hassan, Ashraf Aly,Scheckel, Kirk G.,Suidan, Makram T.,&Tolaymat, Thabet M..(2013).Key Factors Controlling the Transport of Silver Nanoparticles in Porous Media.ENVIRONMENTAL SCIENCE & TECHNOLOGY,47(9),4039-4045.
MLA El Badawy, Amro M.,et al."Key Factors Controlling the Transport of Silver Nanoparticles in Porous Media".ENVIRONMENTAL SCIENCE & TECHNOLOGY 47.9(2013):4039-4045.
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