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DOI | 10.1016/j.atmosenv.2012.09.072 |
"Transference ratios" to predict total oxidized sulfur and nitrogen deposition - Part I, monitoring results | |
Sickles, Joseph E., II1; Shadwick, Douglas S.2 | |
发表日期 | 2013-10-01 |
ISSN | 1352-2310 |
卷号 | 77页码:1060-1069 |
英文摘要 | The "transference ratio" has been defined as the ratio of total (i.e., dry plus wet) deposition to the airborne concentration of a species of interest and introduced as a metric to help estimate total deposition, given airborne concentration (US EPA, 2011). Use of model-predicted transference ratios is currently under consideration by the US EPA in the formulation of a Secondary National Ambient Air Quality Standard for oxidized nitrogen and oxidized sulfur. Since little is known about transference ratios, their behavior is examined in the current study using monitoring data. This term is defined for oxidized sulfur (T-S) as the ratio of the total oxidized sulfur deposition (from dry plus wet deposition) to the airborne concentration of oxidized sulfur. A 15-year record of weekly measured and data-derived quantities at 12 monitoring sites in the eastern US was examined to determine the variability of T-S that might be expected from field measurements. Weekly T-S displayed considerable variability that depended on site, season, and year, but ANOVA results suggest most heavily on site and season. Using weekly data, the variability of deposition-related quantities and error propagation analysis of T-S both suggest that variation in parameters related to wet deposition processes are generally more important than variation in parameters related to dry deposition processes in determining variation in T-S. Correlations between airborne seasonal concentration of oxidized sulfur and the various components of seasonal deposition (i.e., dry, wet, and total) also underscore the strong influence that the variability in wet deposition processes can have on estimates of total deposition. Analysis of monitoring results suggests that 95% confidence intervals for T-S using weekly results over several years for a specific site and season could be as large as +/-235%, but only as large as +/-33% using annual aggregates for a specific site. At the annual scale, a regression model of the form that incorporates a site-specific transference ratio, yielded estimates of total oxidized sulfur deposition to within +25% of the monitored values >= 95% of the time. Since all of the major oxidized nitrogen species are not monitored regularly, a parallel analysis was limited to only the monitored oxidized nitrogen species (OxN). Nevertheless, findings for OxN are consistent with those described above for oxidized sulfur. These results suggest that at specific sites in the eastern US, annual estimates of total deposition to within +/-25 to +/-35% may be expected using species- and site-specific transference ratios along with annual average monitored airborne concentrations. Published by Elsevier Ltd. |
英文关键词 | Transference ratio;Oxidized sulfur;Oxidized nitrogen;Total deposition;CASTNET;NADP |
语种 | 英语 |
WOS记录号 | WOS:000324848500110 |
来源期刊 | ATMOSPHERIC ENVIRONMENT
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来源机构 | 美国环保署 |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/57195 |
作者单位 | 1.US EPA ORD NERL ESD, Landscape Characterizat Branch, Res Triangle Pk, NC 27711 USA; 2.Comp Sci Corp, Durham, NC 27713 USA |
推荐引用方式 GB/T 7714 | Sickles, Joseph E., II,Shadwick, Douglas S.. "Transference ratios" to predict total oxidized sulfur and nitrogen deposition - Part I, monitoring results[J]. 美国环保署,2013,77:1060-1069. |
APA | Sickles, Joseph E., II,&Shadwick, Douglas S..(2013)."Transference ratios" to predict total oxidized sulfur and nitrogen deposition - Part I, monitoring results.ATMOSPHERIC ENVIRONMENT,77,1060-1069. |
MLA | Sickles, Joseph E., II,et al.""Transference ratios" to predict total oxidized sulfur and nitrogen deposition - Part I, monitoring results".ATMOSPHERIC ENVIRONMENT 77(2013):1060-1069. |
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