气候变化领域集成服务门户(CCPortal): Metal-Free Multi-Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin-2-One-Containing Vinyl Sulfones under Visible-Light Photoredox Catalysis

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DOI	10.1002/adsc.202100876
	Metal-Free Multi-Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin-2-One-Containing Vinyl Sulfones under Visible-Light Photoredox Catalysis
	Lv, Yufen; Luo, Jinyun; Lin, Muze; He, Lin; Yue, Huilan; Liu, Ruisheng; Wei, Wei
通讯作者	He, L ; Yue, HL (通讯作者)，Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832000, Xinjiang Uygur, Peoples R China. ; Wei, W (通讯作者)，Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China. ; Wei, W (通讯作者)，Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China. ; Wei, W (通讯作者)，Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.
发表日期	2021
ISSN	1615-4150
EISSN	1615-4169
起始页码	5122
结束页码	5128
卷号	363 期号:22
英文摘要	A metal-free multi-component sulfur dioxide insertion reaction of alkynes, sodium metabisulfite, aryldiazonium, and quinoxalin-2-ones has been developed under visible-light photoredox-catalysis. This photocatalytic tandem reaction would be conducted at room temperature by using of Rhodamine 6G as organic photocatalyst and sodium metabisulfite as the SO2 surrogate. This protocol provides a synthetic strategy for the construction of various quinoxalin-2-one-containing vinyl sulfones with favourable functional group tolerance, in which one C-C bond and two C-S bonds were constructed in one pot procedure.
关键词	SODIUM METABISULFITE ASYMMETRIC HYDROGENATION (E)-VINYL SULFONES QUINOXALIN-2(1H)-ONES ALKYNES ACIDS SULFOXIDES ALKENES THIOLS POTENT
英文关键词	Visible-light-photoredox-catalysis; Quinoxalin-2-ones; Vinyl sulfones; Multi-component reaction; Sodium metabisulfite
语种	英语
WOS研究方向	Chemistry
WOS类目	Chemistry, Applied ; Chemistry, Organic
WOS记录号	WOS:000697962500001
来源期刊	ADVANCED SYNTHESIS & CATALYSIS
来源机构	中国科学院西北生态环境资源研究院
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/253789
作者单位	[Lv, Yufen; Luo, Jinyun; Lin, Muze; He, Lin; Yue, Huilan] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832000, Xinjiang Uygur, Peoples R China; [Wei, Wei] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China; [Wei, Wei] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China; [Lv, Yufen; Liu, Ruisheng; Wei, Wei] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China
推荐引用方式 GB/T 7714	Lv, Yufen,Luo, Jinyun,Lin, Muze,et al. Metal-Free Multi-Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin-2-One-Containing Vinyl Sulfones under Visible-Light Photoredox Catalysis[J]. 中国科学院西北生态环境资源研究院,2021,363(22).
APA	Lv, Yufen.,Luo, Jinyun.,Lin, Muze.,He, Lin.,Yue, Huilan.,...&Wei, Wei.(2021).Metal-Free Multi-Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin-2-One-Containing Vinyl Sulfones under Visible-Light Photoredox Catalysis.ADVANCED SYNTHESIS & CATALYSIS,363(22).
MLA	Lv, Yufen,et al."Metal-Free Multi-Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin-2-One-Containing Vinyl Sulfones under Visible-Light Photoredox Catalysis".ADVANCED SYNTHESIS & CATALYSIS 363.22(2021).