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DOI10.1126/science.281.5383.1646
A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide
Sato K.; Aoki M.; Noyori R.
发表日期1998
ISSN0036-8075
起始页码1646
结束页码1647
卷号281期号:5383
英文摘要Currently, the industrial production of adipic acid users nitric acid oxidation of cyclohexanol or a cyclohexanol/cyclohexanone mixture. The nitrous oxide emission from this process measurably contributes to global warming and ozone depletion. Therefore, the development of an adipic acid production process that is less damaging to the environment is an important subject in chemical research. Cyclohexene can now be oxidized directly to colorless crystalline adipic acid with aqueous 30 percent hydrogen peroxide under organic solvent-and halide-free conditions, which could provide an ideal solution to this serious problem.
英文关键词adipic acid; cyclohexanol; cyclohexanone; hydrogen peroxide; ozone; article; chemical reaction; greenhouse effect; oxidation; ozone layer; priority journal; reaction analysis
语种英语
来源期刊Science
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/245345
作者单位Department of Chemistry, Res. Center for Materials Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan
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Sato K.,Aoki M.,Noyori R.. A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide[J],1998,281(5383).
APA Sato K.,Aoki M.,&Noyori R..(1998).A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide.Science,281(5383).
MLA Sato K.,et al."A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide".Science 281.5383(1998).
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