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DOI | 10.1126/science.281.5383.1646 |
A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide | |
Sato K.; Aoki M.; Noyori R. | |
发表日期 | 1998 |
ISSN | 0036-8075 |
起始页码 | 1646 |
结束页码 | 1647 |
卷号 | 281期号:5383 |
英文摘要 | Currently, the industrial production of adipic acid users nitric acid oxidation of cyclohexanol or a cyclohexanol/cyclohexanone mixture. The nitrous oxide emission from this process measurably contributes to global warming and ozone depletion. Therefore, the development of an adipic acid production process that is less damaging to the environment is an important subject in chemical research. Cyclohexene can now be oxidized directly to colorless crystalline adipic acid with aqueous 30 percent hydrogen peroxide under organic solvent-and halide-free conditions, which could provide an ideal solution to this serious problem. |
英文关键词 | adipic acid; cyclohexanol; cyclohexanone; hydrogen peroxide; ozone; article; chemical reaction; greenhouse effect; oxidation; ozone layer; priority journal; reaction analysis |
语种 | 英语 |
来源期刊 | Science
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/245345 |
作者单位 | Department of Chemistry, Res. Center for Materials Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan |
推荐引用方式 GB/T 7714 | Sato K.,Aoki M.,Noyori R.. A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide[J],1998,281(5383). |
APA | Sato K.,Aoki M.,&Noyori R..(1998).A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide.Science,281(5383). |
MLA | Sato K.,et al."A 'green' route to adipic acid: Direct oxidation of cyclohexenes with 30 percent hydrogen peroxide".Science 281.5383(1998). |
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