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DOI | 10.1039/d0ee03916k |
Hard carbon for sodium storage: Mechanism and optimization strategies toward commercialization | |
Chen D.; Zhang W.; Luo K.; Song Y.; Zhong Y.; Liu Y.; Wang G.; Zhong B.; Wu Z.; Guo X. | |
发表日期 | 2021 |
ISSN | 17545692 |
起始页码 | 2244 |
结束页码 | 2262 |
卷号 | 14期号:4 |
英文摘要 | Sodium-ion batteries (SIBs) have shown promising prospects for complementarity to lithium-ion batteries (LIBs) in the field of grid-scale energy storage. After a decade of continuous fundamental research on SIBs, it's becoming increasingly urgent to advance the commercialization. For SIB anode materials, hard carbon is the most mature and currently the only material likely to be commercialized, but it is still far away from large-scale industrialization. Herein, we carry out a comprehensive overview of the current state of the art in terms of three main aspects. Firstly, a fundamental understanding of the microstructure and sodium storage mechanism of hard carbon is introduced, which can be categorized into three different processes: capacitive adsorption, nanopore filling, and intercalation in carbon interlayers. Then, based on an in-depth understanding of the sodium storage mechanism, optimization methods in terms of increasing the specific capacity, rate performance, initial coulombic efficiency (ICE), and long-cycling stability are comprehensively summarized and analyzed. Finally, potential methods and associated benefits for the design of carbon structures and the solid electrolyte interface (SEI) are discussed, hoping to provide useful guidelines for future research and commercialization. This journal is © The Royal Society of Chemistry. |
英文关键词 | Anodes; Carbon; Energy storage; Lithium-ion batteries; Metal ions; Sodium-ion batteries; Solid electrolytes; Cycling stability; Fundamental research; In-depth understanding; Initial Coulombic efficiency; Optimization method; Optimization strategy; Solid electrolyte interfaces; Specific capacities; Storage (materials); carbon; commercialization; energy storage; optimization; sodium |
语种 | 英语 |
来源期刊 | Energy & Environmental Science
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/190721 |
作者单位 | School of Chemical Engineering, Sichuan University, Chengdu, 610065, China; College of Polymer Science and Engineering, Sichuan University, Chengdu, 610065, China; Key Laboratory of Life-Organic Analysis, Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 273165, China; School of Materials Science and Engineering, Henan Normal University, XinXiang, 453007, China |
推荐引用方式 GB/T 7714 | Chen D.,Zhang W.,Luo K.,et al. Hard carbon for sodium storage: Mechanism and optimization strategies toward commercialization[J],2021,14(4). |
APA | Chen D..,Zhang W..,Luo K..,Song Y..,Zhong Y..,...&Guo X..(2021).Hard carbon for sodium storage: Mechanism and optimization strategies toward commercialization.Energy & Environmental Science,14(4). |
MLA | Chen D.,et al."Hard carbon for sodium storage: Mechanism and optimization strategies toward commercialization".Energy & Environmental Science 14.4(2021). |
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