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DOI	10.1039/d0ee03527k
	In situ polymerization process: An essential design tool for lithium polymer batteries
	Vijayakumar V.; Anothumakkool B.; Kurungot S.; Winter M.; Nair J.R.
发表日期	2021
ISSN	17545692
起始页码	2708
结束页码	2788
卷号	14 期号:5
英文摘要	Polymer electrolytes (PEs), a type of solid-state electrolytes (SSEs), have been in contention for nearly half a century to replace organic liquid electrolytes (LEs) that are used in state-of-the-art lithium-ion batteries (LIBs). They are envisaged to accelerate the industrial-scale production of safe, energy-dense, flexible, and thin lithium polymer batteries (LPBs). LPBs are expected to be widely employed for electric propulsion and other futuristic applications, such as flexible electronics and the Internet of Things (IoT). Even though several polymer architectures and chemistries have been attempted so far, PEs that can outperform LEs remain a real challenge. Apart from inadequate Li+-ion transport properties, challenges concerning the integration of PEs and the engineering of compatible, robust, and durable interfaces and interphases at both the electrodes of LPBs must be appropriately addressed. Recently, the in situ polymerization process has been widely employed as a robust fabrication tool for surpassing the intricacies related to the integration of PEs in LPBs. Hence, in this review, we focus on the in situ polymerization processes that employ various polymerization methods (e.g., free-radical polymerization, ionic polymerization, electropolymerization, condensation polymerization, etc.), functional monomers and oligomers (e.g., acrylate, methacrylate, allyl and vinyl ethers, epoxides, etc.), and PE integration strategies for the fabrication of lithium (ion and metal) polymer batteries (LIPBs and LMPBs). Additionally, this review also evaluates the approaches that have been developed until now to implement the in situ processing of LPBs from large-sized pouch cells to flexible-/printable-batteries and even microbatteries. © 2021 The Royal Society of Chemistry.
英文关键词	Electropolymerization; Flexible electronics; Free radical polymerization; Free radicals; In situ processing; Integration; Internet of things; Ions; Lithium-ion batteries; Polycondensation; Solid electrolytes; Solid-State Batteries; In-situ polymerization process; Industrial-scale production; Integration strategy; Internet of thing (IOT); Ion-transport properties; Organic liquid electrolytes; Polymerization method; Solid-state electrolyte; Polyelectrolytes; detection method; equipment; in situ measurement; lithium; polymer; polymerization
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/190658
作者单位	Helmholtz Institute Münster, IEK-12, Forschungszentrum Jülich GmbH, Corrensstraße 46, Münster, 48149, Germany; Academy of Scientific and Innovative Research (AcSIR), Sector 19 Kamla Nehru Nagar, Ghaziabad Uttar Pradesh, 201002, India; Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune, 411008, India; TNO-Holst Centre, Dutch National Institute for Applied Scientific Research, High Tech Campus 31, Eindhoven, 5656 AE, Netherlands; Meet Battery Research Center, Corrensstraße 46, Münster, 48149, Germany; Institute of Physical Chemistry, University of Münster, Corrensstraße 28/30, Münster, 48149, Germany
推荐引用方式 GB/T 7714	Vijayakumar V.,Anothumakkool B.,Kurungot S.,et al. In situ polymerization process: An essential design tool for lithium polymer batteries[J],2021,14(5).
APA	Vijayakumar V.,Anothumakkool B.,Kurungot S.,Winter M.,&Nair J.R..(2021).In situ polymerization process: An essential design tool for lithium polymer batteries.Energy & Environmental Science,14(5).
MLA	Vijayakumar V.,et al."In situ polymerization process: An essential design tool for lithium polymer batteries".Energy & Environmental Science 14.5(2021).