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DOI10.1039/c8ee00215k
Efficient ternary non-fullerene polymer solar cells with PCE of 11.92% and FF of 76.5%
Zhang M.; Gao W.; Zhang F.; Mi Y.; Wang W.; An Q.; Wang J.; Ma X.; Miao J.; Hu Z.; Liu X.; Zhang J.; Yang C.
发表日期2018
ISSN17545692
起始页码841
结束页码849
卷号11期号:4
英文摘要Non-fullerene polymer solar cells (PSCs) attract more attention due to the constantly refreshed power conversion efficiency (PCE) based on the versatile non-fullerene acceptors. In this work, PCEs of 10.51% and 11.02% were obtained for two kinds of non-fullerene PSC with IDT6CN-M or ITCPTC as the acceptor and PBDB-T as the donor. ITCPTC has a relatively narrow bandgap and a high absorption coefficient compared with IDT6CN-M, which explains well the relatively large short-circuit current density of 17.44 mA cm-2 for the ITCPTC based binary PSCs. Meanwhile, the IDT6CN-M based binary PSCs exhibit a relatively high fill factor (FF) of 75.3% and an open-circuit voltage of 0.915 V. A PCE of 11.92% and a FF of 76.5% were achieved for the ternary PSCs with 60 wt% ITCPTC content in the acceptors, which should be attributed to the enhanced photon harvesting and their good compatibility for a synergistic improvement of exciton utilization and charge transport in the ternary active layers. The FF of 76.5% is among the top values of ternary non-fullerene PSCs. © 2018 The Royal Society of Chemistry.
英文关键词Fullerenes; Open circuit voltage; Polymer solar cells; Absorption co-efficient; Active Layer; Good compatibility; High fill factors; Narrow band gap; Polymer solar cell (PSCs); Power conversion efficiencies; Solar cells; absorption coefficient; carbon; energy efficiency; fuel cell; performance assessment; polymer
语种英语
来源期刊Energy & Environmental Science
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/190284
作者单位Key Laboratory of Luminescence and Optical Information, Ministry of Education, Beijing Jiaotong University, Beijing, 100044, China; Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Department of Chemistry, Wuhan University, Wuhan, 430072, China; Division of Nanophotonics, CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, 100190, China; College of Physics and Electronic Engineering, Taishan University, Taian, 271021, China; Guangxi Key Laboratory of Information Materials, School of Material Science and Technology, Guilin University of Electronic Technology, Guilin, 541004, China
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GB/T 7714
Zhang M.,Gao W.,Zhang F.,et al. Efficient ternary non-fullerene polymer solar cells with PCE of 11.92% and FF of 76.5%[J],2018,11(4).
APA Zhang M..,Gao W..,Zhang F..,Mi Y..,Wang W..,...&Yang C..(2018).Efficient ternary non-fullerene polymer solar cells with PCE of 11.92% and FF of 76.5%.Energy & Environmental Science,11(4).
MLA Zhang M.,et al."Efficient ternary non-fullerene polymer solar cells with PCE of 11.92% and FF of 76.5%".Energy & Environmental Science 11.4(2018).
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