气候变化领域集成服务门户(CCPortal): Environmental and economical perspectives of a glycerol biorefinery

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DOI	10.1039/c7ee03116e
	Environmental and economical perspectives of a glycerol biorefinery
	Lari G.M.; Pastore G.; Haus M.; Ding Y.; Papadokonstantakis S.; Mondelli C.; Pérez-Ramírez J.
发表日期	2018
ISSN	17545692
起始页码	1012
结束页码	1029
卷号	11 期号:5
英文摘要	Glycerol conversion into chemicals and fuel additives is pursued to valorise a burgeoning by-product in the bioenergy sector. To this aim, heterogeneous catalysts have been developed that enable, in many cases, efficient and green transformations. Still, the evaluation of the environmental and economic footprint that would be associated with their large-scale application has often been neglected, limiting their commercial attractiveness. Furthermore, the impact of integrating different glycerol upgrading routes within a biorefinery, which is highly instrumental to determine the effective sustainability and profitability of biodiesel production from vegetable oils, has not been assessed. Here, the manufacture of the most relevant chemical derivatives of glycerol is considered, i.e., lactic acid, acrylic acid, glycerol carbonate, propanediols, epichlorohydrin and allyl alcohol. State-of-the-art catalysts for each upgrading route are briefly reviewed. Based on their performances, processes are rigorously modelled and relevant indicators, the global warming potential, the cumulative energy demand and the operating costs, quantified by life-cycle analysis. Glycerol-based processes are generally found more attractive than the conventional technologies nowadays applied for the production of the same chemicals, among which the paths to lactic acid and glycerol carbonate are particularly promising. In addition, the process variables mostly contributing to the environmental and cost metrics are identified. Accordingly, future studies should target further optimisation mainly in relation to selectivity, solvent volatility, reactants ratio and catalyst stability. Finally, the processes are integrated simulating a prospective glycerol biorefinery and the advantages deriving from the exchange of heat between the different routes quantified. If the glycerol feed is split equally among all routes the CO2 emissions and energy requirements are decreased by 15 and 32%, respectively, and the profit is increased by 5% as compared to the sum of the individual glycerol-based processes. In order to minimise the ecological impact of the biorefinery, glycerol should be rather divided in an 80:20 mass ratio among 1,2-propanediol and glycerol carbonate production, which are expected to have a significant market size. The innovative approach outlined in this work holds potential to guide both fundamental chemical research and process design in the development of CO2 and other bio-refineries. © 2018 The Royal Society of Chemistry.
英文关键词	Bioconversion; Biodiesel; Carbon dioxide; Carbonation; Catalyst selectivity; Cost benefit analysis; Fuel additives; Global warming; Lactic acid; Life cycle; Operating costs; Profitability; Refining; Sustainable development; Biodiesel production; Cumulative energy demands; Energy requirements; Global warming potential; Glycerol conversions; Heterogeneous catalyst; Innovative approaches; Large-scale applications; Glycerol
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/190258
作者单位	Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zurich, Vladimir-Prelog-Weg 1, Zurich, 8093, Switzerland; Division of Energy Technology, Department of Space, Earth and Environment, Chalmers University of Technology, Hörsalsvägen 7B, Gothenburg, 41296, Sweden
推荐引用方式 GB/T 7714	Lari G.M.,Pastore G.,Haus M.,et al. Environmental and economical perspectives of a glycerol biorefinery[J],2018,11(5).
APA	Lari G.M..,Pastore G..,Haus M..,Ding Y..,Papadokonstantakis S..,...&Pérez-Ramírez J..(2018).Environmental and economical perspectives of a glycerol biorefinery.Energy & Environmental Science,11(5).
MLA	Lari G.M.,et al."Environmental and economical perspectives of a glycerol biorefinery".Energy & Environmental Science 11.5(2018).