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DOI	10.1039/c8ee01085d
	An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage
	Allendorf M.D.; Hulvey Z.; Gennett T.; Ahmed A.; Autrey T.; Camp J.; Seon Cho E.; Furukawa H.; Haranczyk M.; Head-Gordon M.; Jeong S.; Karkamkar A.; Liu D.-J.; Long J.R.; Meihaus K.R.; Nayyar I.H.; Nazarov R.; Siegel D.J.; Stavila V.; Urban J.J.; Veccham S.P.; Wood B.C.
发表日期	2018
ISSN	17545692
起始页码	2784
结束页码	2812
卷号	11 期号:10
英文摘要	Nanoporous adsorbents are a diverse category of solid-state materials that hold considerable promise for vehicular hydrogen storage. Although impressive storage capacities have been demonstrated for several materials, particularly at cryogenic temperatures, materials meeting all of the targets established by the U.S. Department of Energy have yet to be identified. In this Perspective, we provide an overview of the major known and proposed strategies for hydrogen adsorbents, with the aim of guiding ongoing research as well as future new storage concepts. The discussion of each strategy includes current relevant literature, strengths and weaknesses, and outstanding challenges that preclude implementation. We consider in particular metal-organic frameworks (MOFs), including surface area/volume tailoring, open metal sites, and the binding of multiple H2 molecules to a single metal site. Two related classes of porous framework materials, covalent organic frameworks (COFs) and porous aromatic frameworks (PAFs), are also discussed, as are graphene and graphene oxide and doped porous carbons. We additionally introduce criteria for evaluating the merits of a particular materials design strategy. Computation has become an important tool in the discovery of new storage materials, and a brief introduction to the benefits and limitations of computational predictions of H2 physisorption is therefore presented. Finally, considerations for the synthesis and characterization of hydrogen storage adsorbents are discussed. © 2018 The Royal Society of Chemistry.
英文关键词	Adsorbents; Binding sites; Crystalline materials; Graphene; Organometallics; Porous materials; Computational predictions; Covalent organic frameworks; Cryogenic temperatures; Metalorganic frameworks (MOFs); Solid-state materials; Synthesis and characterizations; U.S. Department of Energy; Vehicular hydrogen storage; Hydrogen storage; accuracy assessment; adsorption; assessment method; hydrogen; strategic approach; temperature effect
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/190115
作者单位	Energy and Transport Technology Center, Sandia National Laboratories, Livermore, CA 94551, United States; Fuel Cell Technologies Office, U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Washington, DC 20585, United States; Oak Ridge Institute for Science and Education, Washington, DC 20585, United States; Department of Chemistry, Colorado School of Mines, Golden, CO 80401, United States; National Renewable Energy Laboratory, Golden, CO 80401, United States; Mechanical Engineering Department, University of Michigan, Ann Arbor, MI 48109, United States; Pacific Northwest National Laboratory, Richland, WA 99354, United States; Computational Research Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, United States; Department of Chemistry, University of California, Berkeley, CA 94720, United States; Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, United States; Chemical Sciences Division, Lawrence Berkeley National ...
推荐引用方式 GB/T 7714	Allendorf M.D.,Hulvey Z.,Gennett T.,et al. An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage[J],2018,11(10).
APA	Allendorf M.D..,Hulvey Z..,Gennett T..,Ahmed A..,Autrey T..,...&Wood B.C..(2018).An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage.Energy & Environmental Science,11(10).
MLA	Allendorf M.D.,et al."An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage".Energy & Environmental Science 11.10(2018).