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DOI | 10.1039/c8ee01373j |
Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries | |
Zhao Y.; Adair K.R.; Sun X. | |
发表日期 | 2018 |
ISSN | 17545692 |
起始页码 | 2673 |
结束页码 | 2695 |
卷号 | 11期号:10 |
英文摘要 | Rechargeable Na-based battery systems, including Na-ion batteries, room temperature Na-S, Na-O2, Na-CO2, and all-solid-state Na metal batteries, have attracted significant attention due to the high energy density, abundance, low cost, and suitable redox potential of Na metal. However, the Na metal anode faces several challenges, including: (1) the formation of Na dendrites and short circuiting; (2) low Coulombic efficiency (CE) and poor cycling performance; and (3) an infinite volume change due to its hostless nature. Furthermore, the issues associated with Na metal anodes have also been noticed in practical Na metal batteries (NMBs). In recent years, the importance of the Na metal anode has been highlighted and many studies have provided potential solutions to address the issues of its use. This review article focuses on the recent developments of Na metal anodes, including insight into the fundamental understanding of its electrochemical processes, novel characterization methods, approaches for protecting the anode and future perspectives. Our review will accelerate further improvement in the characterization and application of Na metal anodes for next-generation NMB systems. © 2018 The Royal Society of Chemistry. |
英文关键词 | Anodes; Redox reactions; Secondary batteries; Characterization methods; Coulombic efficiency; Cycling performance; Electrochemical process; Future perspectives; High energy densities; Redox potentials; Short circuiting; Metals; efficiency measurement; electrochemical method; electrode; equipment; performance assessment; redox potential; sodium; temperature effect; volume change |
语种 | 英语 |
来源期刊 | Energy & Environmental Science
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/190113 |
作者单位 | Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON N6A 5B9, Canada |
推荐引用方式 GB/T 7714 | Zhao Y.,Adair K.R.,Sun X.. Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries[J],2018,11(10). |
APA | Zhao Y.,Adair K.R.,&Sun X..(2018).Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries.Energy & Environmental Science,11(10). |
MLA | Zhao Y.,et al."Recent developments and insights into the understanding of Na metal anodes for Na-metal batteries".Energy & Environmental Science 11.10(2018). |
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