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DOI	10.1039/c8ee03651a
	The potential of electrolyte filled MOF membranes as ionic sieves in rechargeable batteries
	He Y.; Qiao Y.; Chang Z.; Zhou H.
发表日期	2019
ISSN	17545692
起始页码	2327
结束页码	2344
卷号	12 期号:8
英文摘要	Metal-organic frameworks (MOFs), also known as porous coordination polymers, are constructed using metal-containing nodes with organic bridges. With intrinsically ordered porous structure, MOFs are considered as a promising component to modify separator/electrolyte systems for rechargeable batteries. Herein, drawing upon the information collected from recent reports, we analysed and discussed the effects of MOF-based membranes on ion transmission. Both simulation calculations and experimental results indicated that the liquid electrolyte filled MOF membranes could aid in guiding the uniformity of Li ion plating, suppressing the growth of Li dendrites. More importantly, the applications of MOF-based membranes in Li-metal battery and Li-ion battery systems were also overviewed by collecting state-of-art research results. When the MOF-based membranes were used as separators, they can not only successfully restrain the adverse shuttling of electrochemical intermediate products for achieving long cycle life Li-S batteries, but can also be used to develop dual-mediator strategies for superior electrochemical performance Li-O2 batteries and hybrid electrolyte systems for high voltage Li-ion batteries. In addition, based on the obtained progress in rechargeable lithium batteries, the potential of MOF-based membranes serving as ionic sieves in Na-metal batteries, organic redox flow batteries and liquid-anode batteries was rationally proposed. Finally, several suggestions in regard to constructing reliable batteries with MOF membranes were provided from the perspective of practical applications. © The Royal Society of Chemistry 2019.
英文关键词	Crystalline materials; Electrolytes; Flow batteries; Ions; Lithium compounds; Lithium sulfur batteries; Lithium-air batteries; Membranes; Metals; Organic polymers; Organometallics; Sieves; Sulfur compounds; Electrochemical performance; Hybrid electrolytes; Intermediate product; Liquid electrolytes; Metalorganic frameworks (MOFs); Porous coordination polymer; Rechargeable lithium battery; Simulation calculation; Lithium-ion batteries; cation; electrolyte; energy storage; lithium; organic compound; porous medium; research work
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189843
作者单位	Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Umezono, Tsukuba, 305-8568, Japan; Graduate School of System and Information Engineering, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, 305-8573, Japan; Center of Energy Storage Materials and Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, 210093, China
推荐引用方式 GB/T 7714	He Y.,Qiao Y.,Chang Z.,et al. The potential of electrolyte filled MOF membranes as ionic sieves in rechargeable batteries[J],2019,12(8).
APA	He Y.,Qiao Y.,Chang Z.,&Zhou H..(2019).The potential of electrolyte filled MOF membranes as ionic sieves in rechargeable batteries.Energy & Environmental Science,12(8).
MLA	He Y.,et al."The potential of electrolyte filled MOF membranes as ionic sieves in rechargeable batteries".Energy & Environmental Science 12.8(2019).