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DOI10.1039/c9ee03828k
Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries
Li X.; Liang J.; Yang X.; Adair K.R.; Wang C.; Zhao F.; Sun X.
发表日期2020
ISSN17545692
起始页码1429
结束页码1461
卷号13期号:5
英文摘要Halide solid-state electrolytes (SSEs) with high room-temperature ionic conductivity (>10-3 S cm-1), wide electrochemical windows, and good compatibility toward oxide cathode materials have achieved impressive progress and attracted significant attention for application in all-solid-state lithium batteries (ASSLBs). This review presents an overview of halide SSEs, including their development, structure, ionic conductivity, chemical stability, and current limitations. Firstly, we give a brief overview of the historical development of halide-based SSEs, followed by an introduction to the different types of halide SSEs. From a practical point of view, the synthesis methods, especially scalable liquid-phase synthesis, are intensively discussed. Then, the associated stability issues involving basic structure stability, air/humidity stability, and electrochemical stability (electrolyte/SSE interface and electrochemical stability window) are also discussed in detail. Comprehensive coverage and thorough understanding of the properties of halide SSEs are provided and it is expected to help guide the development of future SSEs towards ASSLBs for energy storage applications. © The Royal Society 2020 of Chemistry.
英文关键词Cathodes; Chemical stability; Energy storage; Ionic conduction in solids; Ionic conductivity; Lithium batteries; Solid-State Batteries; All-solid-state lithium battery; Electrochemical stabilities; Electrochemical window; Energy storage applications; Historical development; Liquid-phase synthesis; Lithium conductors; Solid-state electrolyte; Solid electrolytes; detection method; equipment; halide; lithium; operations technology; performance assessment
语种英语
来源期刊Energy & Environmental Science
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/189718
作者单位Department of Mechanical and Materials Engineering, University of Western Ontario, 1151 Richmond St, London, ON N6A 3K7, Canada
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GB/T 7714
Li X.,Liang J.,Yang X.,et al. Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries[J],2020,13(5).
APA Li X..,Liang J..,Yang X..,Adair K.R..,Wang C..,...&Sun X..(2020).Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries.Energy & Environmental Science,13(5).
MLA Li X.,et al."Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries".Energy & Environmental Science 13.5(2020).
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