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DOI | 10.1039/c9ee03828k |
Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries | |
Li X.; Liang J.; Yang X.; Adair K.R.; Wang C.; Zhao F.; Sun X. | |
发表日期 | 2020 |
ISSN | 17545692 |
起始页码 | 1429 |
结束页码 | 1461 |
卷号 | 13期号:5 |
英文摘要 | Halide solid-state electrolytes (SSEs) with high room-temperature ionic conductivity (>10-3 S cm-1), wide electrochemical windows, and good compatibility toward oxide cathode materials have achieved impressive progress and attracted significant attention for application in all-solid-state lithium batteries (ASSLBs). This review presents an overview of halide SSEs, including their development, structure, ionic conductivity, chemical stability, and current limitations. Firstly, we give a brief overview of the historical development of halide-based SSEs, followed by an introduction to the different types of halide SSEs. From a practical point of view, the synthesis methods, especially scalable liquid-phase synthesis, are intensively discussed. Then, the associated stability issues involving basic structure stability, air/humidity stability, and electrochemical stability (electrolyte/SSE interface and electrochemical stability window) are also discussed in detail. Comprehensive coverage and thorough understanding of the properties of halide SSEs are provided and it is expected to help guide the development of future SSEs towards ASSLBs for energy storage applications. © The Royal Society 2020 of Chemistry. |
英文关键词 | Cathodes; Chemical stability; Energy storage; Ionic conduction in solids; Ionic conductivity; Lithium batteries; Solid-State Batteries; All-solid-state lithium battery; Electrochemical stabilities; Electrochemical window; Energy storage applications; Historical development; Liquid-phase synthesis; Lithium conductors; Solid-state electrolyte; Solid electrolytes; detection method; equipment; halide; lithium; operations technology; performance assessment |
语种 | 英语 |
来源期刊 | Energy & Environmental Science
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/189718 |
作者单位 | Department of Mechanical and Materials Engineering, University of Western Ontario, 1151 Richmond St, London, ON N6A 3K7, Canada |
推荐引用方式 GB/T 7714 | Li X.,Liang J.,Yang X.,et al. Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries[J],2020,13(5). |
APA | Li X..,Liang J..,Yang X..,Adair K.R..,Wang C..,...&Sun X..(2020).Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries.Energy & Environmental Science,13(5). |
MLA | Li X.,et al."Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries".Energy & Environmental Science 13.5(2020). |
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