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DOI	10.1039/d0ee00060d
	A stable high-voltage lithium-ion battery realized by an in-built water scavenger
	Chang Z.; Qiao Y.; Deng H.; Yang H.; He P.; Zhou H.
发表日期	2020
ISSN	17545692
起始页码	1197
结束页码	1204
卷号	13 期号:4
英文摘要	Induced by the hydrolysis of electrolytes, hydrofluoric acid (HF) can exacerbate the notorious transition metal dissolution, which seriously restricts the development of high-energy-density lithium batteries based on high-voltage cathodes. Irremovable water, not limited to trace water originally contained in electrolytes, can also be continuously produced upon battery fabrication and electrochemical cycling processes, which has been ignored for a long time. Herein, exempting cells from cumbersome and time-consuming industrial water-removal procedures, we simply introduced a metal-organic framework (MOF) into the inside of cells as an effective in-built water scavenger. As a result, pairing the in-built water scavengers with various high-voltage cathodes (LiNi0.5Mn1.5O4, LiNi0.8Co0.1Mn0.1O2, etc.), we demonstrated superior cycling stability (72% capacity retention after 400 cycles for LiNi0.8Co0.1Mn0.1O2, calculated from the 4th cycle after 3 cycles of activation) even under a harsh environment (200 ppm water containing electrolyte). Simply using a MOF as a water scavenger can simultaneously reduce the manufacturing costs of lithium-ion batteries while improving their lifespan and safety. © The Royal Society of Chemistry.
英文关键词	Cathodes; Chemicals removal (water treatment); Electrolytes; Hydrofluoric acid; Manufacture; Metal-Organic Frameworks; Organometallics; Transition metals; Capacity retention; Cycling stability; Electrochemical cycling; Harsh environment; High energy densities; High voltage cathode; Manufacturing cost; Metal dissolution; Lithium-ion batteries; chemical compound; electrode; electrolyte; equipment; hydrofluoric acid; hydrolysis; lithium; manufacturing; pollutant removal; transition element
语种	英语
来源期刊	Energy & Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/189666
作者单位	Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1, Umezono, Tsukuba, 305-8568, Japan; Graduate School of System and Information Engineering, University of Tsukuba, 1-1-1, Tennoudai, Tsukuba, 305-8573, Japan; Center of Energy Storage Materials and Technology, College of Engineering and Applied Sciences, Jiangsu Key Laboratory of Artificial Functional Materials, National Laboratory of Solid State Micro-structures, Collaborative Innovation Center of Advanced Micro-structures, Nanjing University, Nanjing, 210093, China
推荐引用方式 GB/T 7714	Chang Z.,Qiao Y.,Deng H.,et al. A stable high-voltage lithium-ion battery realized by an in-built water scavenger[J],2020,13(4).
APA	Chang Z.,Qiao Y.,Deng H.,Yang H.,He P.,&Zhou H..(2020).A stable high-voltage lithium-ion battery realized by an in-built water scavenger.Energy & Environmental Science,13(4).
MLA	Chang Z.,et al."A stable high-voltage lithium-ion battery realized by an in-built water scavenger".Energy & Environmental Science 13.4(2020).