气候变化领域集成服务门户(CCPortal): Magnetism of Body-Centered Cubic Fe-Ni Alloys Under Pressure: Strain-Enhanced Ferromagnetism at the Phase Transitions

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DOI	10.1029/2020JB020922
	Magnetism of Body-Centered Cubic Fe-Ni Alloys Under Pressure: Strain-Enhanced Ferromagnetism at the Phase Transitions
	Wei Q.; Gilder S.A.; Ertel-Ingrisch W.; Guillou F.; Wilhelm F.
发表日期	2020
ISSN	21699313
卷号	125 期号:12
英文摘要	We investigated the magnetism of body-centered cubic (bcc) FeNi alloys (Fe92Ni08, Fe87Ni13, and Fe84Ni16) as a function of pressure at room temperature through the bcc to hexagonal closed packed (hcp) phase transition. In each case, the fully saturated magnetic remanence attained maxima, 3–6 times higher than the initial value, at the hysteretic bcc → hcp and hcp → bcc transition boundaries upon compression and decompression. Magnetization maxima generally shifted to lower pressures with increasing Ni, concurrent with the phase transition. In Fe84Ni16, X-ray magnetic circular dichroism (XMCD) at the K-edge of Fe measured in a 2.5 T field together with X-ray absorption spectroscopy indicate that the magnetism defined by XMCD divided by the proportion of bcc also attains a maximum in the transition regions, similar to the magnetic remanence measurements. Enhanced remanence is attributed to a lattice mismatch between bcc-Fe and hcp-Fe phases together with defect-riddled martensite. This mechanism also explains why the remanence of bcc FeNi is 2–4 times stronger at full decompression than initially, which bears on the interpretation of paleointensity records of meteorites containing bcc FeNi alloys (kamacite). Only techniques that probe magnetic states carried out in fully saturating external fields detect magnetic signals in bcc-Fe residing in the hcp stability region, thereby explaining the discrepancy among the experimental results. How far in pressure bcc-Fe persists into the hcp stability field, especially at elevated temperatures, remains open. © 2020 The Authors.
英文关键词	iron; magnetism; nickel; phase transition; pressure; remanence
语种	英语
来源期刊	Journal of Geophysical Research: Solid Earth
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/187480
作者单位	Department of Earth and Environmental Sciences, Ludwig-Maximilians-Universität, Munich, Germany; European Synchrotron Radiation Facility, Grenoble Cedex 9, France
推荐引用方式 GB/T 7714	Wei Q.,Gilder S.A.,Ertel-Ingrisch W.,et al. Magnetism of Body-Centered Cubic Fe-Ni Alloys Under Pressure: Strain-Enhanced Ferromagnetism at the Phase Transitions[J],2020,125(12).
APA	Wei Q.,Gilder S.A.,Ertel-Ingrisch W.,Guillou F.,&Wilhelm F..(2020).Magnetism of Body-Centered Cubic Fe-Ni Alloys Under Pressure: Strain-Enhanced Ferromagnetism at the Phase Transitions.Journal of Geophysical Research: Solid Earth,125(12).
MLA	Wei Q.,et al."Magnetism of Body-Centered Cubic Fe-Ni Alloys Under Pressure: Strain-Enhanced Ferromagnetism at the Phase Transitions".Journal of Geophysical Research: Solid Earth 125.12(2020).