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DOI10.1039/d0dt00514b
Reversible luminescent humidity chromism of organic-inorganic hybrid PEA2MnBr4single crystals
Gao W.; Leng M.; Hu Z.; Li J.; Li D.; Liu H.; Gao L.; Niu G.; Tang J.
发表日期2020
ISSN14779226
起始页码5662
结束页码5668
卷号49期号:17
英文摘要Organic-inorganic hybrids have drawn great attention for gas sensors due to their high sensitivity, good selectivity and acceptable stability at room temperature. There are two main approaches by which organic-inorganic hybrids convert gas information to electric or optical signals (vapochromism). Here, we have reported a new organic-inorganic hybrid PEA2MnBr4for humidity detection by luminescent visible chromism. PEA2MnBr4single crystals were grown by the solution method and determined by single-crystal X-ray diffraction. Luminescent humidity chromism was found on PEA2MnBr4from green emission at the water-desorption state to pink emission at the water-adsorption state within 18 s at a relative humidity of 38% RH. This obviously visible chromism was further used to check the water content in toluene with a low detection limit between 0.02 and 0.05 vol%. © The Royal Society of Chemistry 2020.
scopus关键词Chemical sensors; Luminescence; Single crystals; High sensitivity; Humidity detection; Low detection limit; Organic-inorganic hybrid; Single crystal x-ray diffraction; Solution methods; Water adsorption; Water desorption; organic-inorganic materials
来源期刊Dalton Transactions
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/176913
作者单位Sargent Joint Research Center, Wuhan National Laboratory for Optoelectronics (WNLO) and School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei 430074, China
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Gao W.,Leng M.,Hu Z.,et al. Reversible luminescent humidity chromism of organic-inorganic hybrid PEA2MnBr4single crystals[J],2020,49(17).
APA Gao W..,Leng M..,Hu Z..,Li J..,Li D..,...&Tang J..(2020).Reversible luminescent humidity chromism of organic-inorganic hybrid PEA2MnBr4single crystals.Dalton Transactions,49(17).
MLA Gao W.,et al."Reversible luminescent humidity chromism of organic-inorganic hybrid PEA2MnBr4single crystals".Dalton Transactions 49.17(2020).
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