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DOI | 10.1016/j.jclepro.2019.04.194 |
Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste | |
Lee Y.; Andrew Lin K.-Y.; Kwon E.E.; Lee J. | |
发表日期 | 2019 |
ISSN | 9596526 |
起始页码 | 624 |
结束页码 | 633 |
卷号 | 227 |
英文摘要 | Renewable chemicals, which could potentially replace crude oil-derived chemicals, have been receiving increased interest due to their environment-friendliness (i.e., carbon neutrality). Nylon 66 and nylon 6 are synthetic polymers that are widely used in daily life, synthesized by polycondensation of adipic acid and hexamethylenediamine (HMDA)and by ring-opening polymerization of ε-caprolactam, respectively. This review assesses catalytic productions of these three monomers from food waste. The food waste-based routes to the target compounds are analyzed separately and compared to conventional petroleum-based routes. Even though no commercially available methods to directly convert food waste into the target molecules exist, we have suggested emerging and promising catalytic routes via combined processes. The proposed pathways for the renewable production of adipic acid, HMDA, and ε-caprolactam are not yet fully competitive with petrochemical pathways due to higher costs and lower process efficiencies. However, considering that the renewable food waste-based routes are still being developed, their commercialization should happen soon. Elsevier Ltd |
英文关键词 | Adipic acid; Biorefinery; Caprolactam; Catalyst; Hexamethylenediamine; Organic waste |
scopus关键词 | Catalysts; Cyclohexane; Molecules; Nylon polymers; Oils and fats; Petrochemicals; Rayon; Adipic acids; Biorefineries; Caprolactam; Hexamethylenediamine; Organic wastes; Ring opening polymerization |
来源期刊 | Journal of Cleaner Production
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/176188 |
作者单位 | Department of Environmental Engineering, Ajou University, Suwon, 16499, South Korea; Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture & Research Center of Sustainable Energy and Nanotechnology, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan; Department of Environment and Energy, Sejong University, Seoul, 05006, South Korea |
推荐引用方式 GB/T 7714 | Lee Y.,Andrew Lin K.-Y.,Kwon E.E.,et al. Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste[J],2019,227. |
APA | Lee Y.,Andrew Lin K.-Y.,Kwon E.E.,&Lee J..(2019).Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste.Journal of Cleaner Production,227. |
MLA | Lee Y.,et al."Renewable routes to monomeric precursors of nylon 66 and nylon 6 from food waste".Journal of Cleaner Production 227(2019). |
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