气候变化领域集成服务门户(CCPortal): Electrochemical conversion of a bio-derivable hydroxy acid to a drop-in oxygenate diesel fuel

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DOI	10.1039/c9ee01485c
	Electrochemical conversion of a bio-derivable hydroxy acid to a drop-in oxygenate diesel fuel
	Meyers J.; Mensah J.B.; Holzhäuser F.J.; Omari A.; Blesken C.C.; Tiso T.; Palkovits S.; Blank L.M.; Pischinger S.; Palkovits R.
发表日期	2019
ISSN	1754-5692
起始页码	2406
结束页码	2411
卷号	12 期号:8
英文摘要	3-Hydroxy decanoic acid (3-HDA), derivable from glucose or xylose waste-streams, was successfully upgraded electrochemically into a drop-in oxygenate with promising fuel characteristics. Properties such as a cetane number of 63 together with a suitable flash point and cold filter plugging point qualify the mixture for high blending ratios with fossil diesel or Fischer-Tropsch diesel. The individual C9 oxygenates are otherwise only accessible by hydroformylation. Under optimised conditions, anodic decarboxylation of 3-HDA allowed near full conversion and over 95% total yield after 30 minutes. Further, direct electrochemical 3-HDA conversion of a fermentation broth was demonstrated. This allows for a substantial reduction of unit operations and energy requirements, highlighting the potential of integrating electrochemistry and biotechnology into future bio-refineries. © The Royal Society of Chemistry 2019.
语种	英语
scopus关键词	Blending; Carboxylation; Drops; Electrochemistry; Fatty acids; Anodic decarboxylation; Cold filter plugging point; Electrochemical conversion; Fermentation broths; Fischer-Tropsch diesel; Fuel characteristics; Optimised conditions; Substantial reduction; Diesel engines; biodegradation; chemical reaction; diesel; electrochemical method; fatty acid; fermentation; fuel; optimization
来源期刊	Energy and Environmental Science
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/162677
作者单位	Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 2, Aachen, 52074, Germany; Lehrstuhl für Verbrennungskraftmaschinen, RWTH Aachen University, Forckenbeckstraße 4, Aachen, 52074, Germany; Institut für Angewandte Mikrobiologie, RWTH Aachen University Worringerweg 1, Aachen, 52074, Germany
推荐引用方式 GB/T 7714	Meyers J.,Mensah J.B.,Holzhäuser F.J.,et al. Electrochemical conversion of a bio-derivable hydroxy acid to a drop-in oxygenate diesel fuel[J],2019,12(8).
APA	Meyers J..,Mensah J.B..,Holzhäuser F.J..,Omari A..,Blesken C.C..,...&Palkovits R..(2019).Electrochemical conversion of a bio-derivable hydroxy acid to a drop-in oxygenate diesel fuel.Energy and Environmental Science,12(8).
MLA	Meyers J.,et al."Electrochemical conversion of a bio-derivable hydroxy acid to a drop-in oxygenate diesel fuel".Energy and Environmental Science 12.8(2019).