气候变化领域集成服务门户(CCPortal): Producing desired ice faces

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DOI	10.1073/pnas.1513173112
	Producing desired ice faces
	Shultz M.J.; Brumberg A.; Bisson P.J.; Shultz R.
发表日期	2015
ISSN	0027-8424
起始页码	E6096
结束页码	E6100
卷号	112 期号:45
英文摘要	The ability to prepare single-crystal faces has become central to developing and testing models for chemistry at interfaces, spectacularly demonstrated by heterogeneous catalysis and nanoscience. This ability has been hampered for hexagonal ice, Ih-A fundamental hydrogen-bonded surface-due to two characteristics of ice: ice does not readily cleave along a crystal lattice plane and properties of ice grown on a substrate can differ significantly from those of neat ice. This work describes laboratory-based methods both to determine the Ih crystal lattice orientation relative to a surface and to use that orientation to prepare any desired face. The work builds on previous results attaining nearly 100% yield of high-quality, single-crystal boules. With these methods, researchers can prepare authentic, single-crystal ice surfaces for numerous studies including uptake measurements, surface reactivity, and catalytic activity of this ubiquitous, fundamental solid.
语种	英语
scopus关键词	Article; catalysis; chemistry; crystal; crystal structure; growth rate; light refraction; mass extinction; measurement; microtome; nanotechnology; polarization; priority journal; simulation; surface property
来源期刊	Proceedings of the National Academy of Sciences of the United States of America
文献类型	期刊论文
条目标识符	http://gcip.llas.ac.cn/handle/2XKMVOVA/159086
作者单位	Shultz, M.J., Laboratory for Water and Surface Studies, Chemistry Department, Tufts University, Medford, MA 02155, United States; Brumberg, A., Laboratory for Water and Surface Studies, Chemistry Department, Tufts University, Medford, MA 02155, United States; Bisson, P.J., Laboratory for Water and Surface Studies, Chemistry Department, Tufts University, Medford, MA 02155, United States; Shultz, R., Laboratory for Water and Surface Studies, Chemistry Department, Tufts University, Medford, MA 02155, United States
推荐引用方式 GB/T 7714	Shultz M.J.,Brumberg A.,Bisson P.J.,et al. Producing desired ice faces[J],2015,112(45).
APA	Shultz M.J.,Brumberg A.,Bisson P.J.,&Shultz R..(2015).Producing desired ice faces.Proceedings of the National Academy of Sciences of the United States of America,112(45).
MLA	Shultz M.J.,et al."Producing desired ice faces".Proceedings of the National Academy of Sciences of the United States of America 112.45(2015).