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DOI10.1016/S1872-2067(18)63155-9
Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries
Yue, Guanghui; Liu, Jiandi; Han, Jiangtao; Qin, Donghui; Chen, Qiang; Shao, Jianxiong
发表日期2018
ISSN0253-9837
起始页码1951
结束页码1959
卷号39期号:12
英文摘要An amorphous CoSnO3@rGO nanocomposite fabricated using a surfactant-assisted assembly method combined with thermal treatment served as a catalyst for non-aqueous lithium-oxygen (Li-O-2) batteries. In contrast to the specific surface area of the bare CoSnO3 nanoboxes (104.3 m(2) g(-1)), the specific surface area of the CoSnO3@rGO nanocomposite increased to approximately 195.8 m2 g1 and the electronic conductivity also improved. The increased specific surface area provided more space for the deposition of Li2O2, while the improved electronic conductivity accelerated the decomposition of Li2O2. Compared to bare CoSnO3, the overpotential reduced by approximately 20 and 60 mV at current densities of 100 and 500 mA g(-1) when CoSnO3@rGO was used as the catalyst. A Li-O-2 battery using a CoSnO3@rGO nanocomposite as the cathode catalyst cycled indicated a superior cyclic stability of approximately 130 cycles at a current density of 200 mA g(-1) with a limited capacity of 1000 mAh g(-1), which is 25 cycles more than that of the bare amorphous CoSnO3 nano boxes. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
英文关键词Amorphous CoSnO3 nanoboxe; Nanocomposite; Li-O-2 battery; Cathode catalyst
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
来源期刊CHINESE JOURNAL OF CATALYSIS
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/158509
作者单位Yue, GH (corresponding author), Xiamen Univ, Dept Mat Sci & Engn, Xiamen 361005, Fujian, Peoples R China.; Chen, Q (corresponding author), Xiamen Univ, Dept Elect Sci, Xiamen 361005, Fujian, Peoples R China.
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GB/T 7714
Yue, Guanghui,Liu, Jiandi,Han, Jiangtao,et al. Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries[J],2018,39(12).
APA Yue, Guanghui,Liu, Jiandi,Han, Jiangtao,Qin, Donghui,Chen, Qiang,&Shao, Jianxiong.(2018).Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries.CHINESE JOURNAL OF CATALYSIS,39(12).
MLA Yue, Guanghui,et al."Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries".CHINESE JOURNAL OF CATALYSIS 39.12(2018).
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