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DOI | 10.1016/S1872-2067(18)63155-9 |
Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries | |
Yue, Guanghui; Liu, Jiandi; Han, Jiangtao; Qin, Donghui; Chen, Qiang; Shao, Jianxiong | |
发表日期 | 2018 |
ISSN | 0253-9837 |
起始页码 | 1951 |
结束页码 | 1959 |
卷号 | 39期号:12 |
英文摘要 | An amorphous CoSnO3@rGO nanocomposite fabricated using a surfactant-assisted assembly method combined with thermal treatment served as a catalyst for non-aqueous lithium-oxygen (Li-O-2) batteries. In contrast to the specific surface area of the bare CoSnO3 nanoboxes (104.3 m(2) g(-1)), the specific surface area of the CoSnO3@rGO nanocomposite increased to approximately 195.8 m2 g1 and the electronic conductivity also improved. The increased specific surface area provided more space for the deposition of Li2O2, while the improved electronic conductivity accelerated the decomposition of Li2O2. Compared to bare CoSnO3, the overpotential reduced by approximately 20 and 60 mV at current densities of 100 and 500 mA g(-1) when CoSnO3@rGO was used as the catalyst. A Li-O-2 battery using a CoSnO3@rGO nanocomposite as the cathode catalyst cycled indicated a superior cyclic stability of approximately 130 cycles at a current density of 200 mA g(-1) with a limited capacity of 1000 mAh g(-1), which is 25 cycles more than that of the bare amorphous CoSnO3 nano boxes. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
英文关键词 | Amorphous CoSnO3 nanoboxe; Nanocomposite; Li-O-2 battery; Cathode catalyst |
WOS研究方向 | Chemistry ; Engineering |
WOS类目 | Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical |
来源期刊 | CHINESE JOURNAL OF CATALYSIS |
文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/158509 |
作者单位 | Yue, GH (corresponding author), Xiamen Univ, Dept Mat Sci & Engn, Xiamen 361005, Fujian, Peoples R China.; Chen, Q (corresponding author), Xiamen Univ, Dept Elect Sci, Xiamen 361005, Fujian, Peoples R China. |
推荐引用方式 GB/T 7714 | Yue, Guanghui,Liu, Jiandi,Han, Jiangtao,et al. Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries[J],2018,39(12). |
APA | Yue, Guanghui,Liu, Jiandi,Han, Jiangtao,Qin, Donghui,Chen, Qiang,&Shao, Jianxiong.(2018).Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries.CHINESE JOURNAL OF CATALYSIS,39(12). |
MLA | Yue, Guanghui,et al."Amorphous CoSnO3@rGO nanocomposite as an efficient cathode catalyst for long-life Li-O-2 batteries".CHINESE JOURNAL OF CATALYSIS 39.12(2018). |
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