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DOI10.1016/j.quascirev.2019.06.037
230Th/U burial dating of ostrich eggshell
Sharp W.D.; Tryon C.A.; Niespolo E.M.; Fylstra N.D.; Tripathy-Lang A.; Faith J.T.
发表日期2019
ISSN0277-3791
起始页码263
结束页码276
卷号219
英文摘要Obtaining precise and accurate dates for late Quaternary terrestrial sequences containing Middle Stone Age or Middle Paleolithic archaeological materials (ca. 30–300 ka) can be challenging. Many such sequences lie beyond the limit of radiocarbon dating (∼50 ka) and lack volcanic ashes suitable for 40Ar/39Ar dating. We report a dating approach with about ten times the range of radiocarbon dating (∼500 ka) based on a novel protocol for 230Th/U dating of ostrich eggshell, a common component of African, Near Eastern and Asian archaeological sequences. Uranium in ostrich eggshell, typically at levels of tens to hundreds of ppb, is acquired after burial. However, accurate burial ages can be determined from measured 230Th/U ages when corrected for uranium uptake via diffusion. Using ostrich eggshells from a Pleistocene-Holocene east African site, we have: (1) characterized the spatial distribution of uranium and common thorium (232Th) concentrations in ostrich eggshell by laser ablation ICP-MS, (2) determined apparent 230Th/U ages on outer and inner layers of eggshells by solution ICP-MS analyses of selectively abraded eggshells, and (3) calculated 230Th/U burial ages using a simple model for diffusive uptake of uranium. We assess our method by comparing the 230Th/U burial ages (median uncertainty 2.3%, 1 SD) with radiocarbon dates on carbonate from the same eggshells. We find good agreement in seven out of nine eggshells, confirming the accuracy of their 230Th/U model ages. Eggshells that fail to yield reliable 230Th/U ages may be recognized by anomalous patterns of apparent 230Th/U ages, providing a reliability criterion innate to the 230Th/U data. Ostrich eggshells are resistant to diagenesis simplifying 230Th/U dating compared to bones and teeth. Eggshells of ostrich, emu, rhea and other living and extinct ratites found on six continents share similar structure and composition, suggesting our new approach to 230Th/U dating of eggshell may be applicable in diverse late Quaternary terrestrial settings. © 2019 Elsevier Ltd
英文关键词Africa; Archaeology; Geochronology; Later stone age; Middle stone age; Ostrich eggshells; Pleistocene; Ratite eggshells; U-series
语种英语
scopus关键词Geochronology; Inductively coupled plasma mass spectrometry; Laser ablation; Mass spectrometers; Uncertainty analysis; Uranium; Volcanoes; Africa; Archaeology; Ostrich eggshells; Pleistocene; Ratite eggshells; Stone age; U-series; Birds; archaeology; eggshell; geochronology; Mesolithic; Paleolithic; Pleistocene-Holocene boundary; Quaternary; radiocarbon dating; spatial distribution; terrestrial environment; uranium series dating; Africa; Asia; Palaeognathae; Rhea; Struthioniformes
来源期刊Quaternary Science Reviews
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/151820
作者单位Berkeley Geochronology Center, 2455 Ridge Road, Berkeley, CA 94709, United States; Department of Anthropology, Harvard University, Cambridge, MA 02138, United States; Department of Earth and Planetary Science, University of California, Berkeley, CA 94720, United States; Natural History Museum of Utah and Department of Anthropology, University of Utah, Salt Lake City, UT 84108, United States
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Sharp W.D.,Tryon C.A.,Niespolo E.M.,et al. 230Th/U burial dating of ostrich eggshell[J],2019,219.
APA Sharp W.D.,Tryon C.A.,Niespolo E.M.,Fylstra N.D.,Tripathy-Lang A.,&Faith J.T..(2019).230Th/U burial dating of ostrich eggshell.Quaternary Science Reviews,219.
MLA Sharp W.D.,et al."230Th/U burial dating of ostrich eggshell".Quaternary Science Reviews 219(2019).
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