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DOI | 10.1016/j.marpolbul.2018.11.052 |
Bioavailability and distribution of PAHs and PCBs in the sediment pore water of the German Bight and Wadden Sea | |
Niehus N.C.; Brockmeyer B.; Witt G. | |
发表日期 | 2019 |
ISSN | 0025326X |
起始页码 | 421 |
结束页码 | 427 |
卷号 | 138 |
英文摘要 | The freely dissolved concentration (Cfree) was measured for PAHs and PCBs in sediments of the German Bight and Wadden Sea. Ex-situ Solid Phase Microextraction (SPME) was applied using Polydimethlysiloxane (PDMS) coated glass fibers followed by automated thermal desorption and GC–MS analysis. This study provides the first dataset on the spatial distribution of Cfree for PAHs and PCBs in the German Bight and the Wadden Sea. We found elevated PCB concentrations in the Wadden Sea and especially in the Weser estuary. Sandy North Sea sediments were rather less contaminated, except for some former dumping sites. The sorption strength of PAHs was generally stronger, while PCBs in the Wadden Sea sediments were only weakly bound. This SPME method is a rapid and sensitive tool to study Cfree of hydrophobic organic chemicals to improve todays sediment risk assessment. © 2018 Elsevier Ltd |
英文关键词 | Baseline toxicity; Bioavailability; Cfree; HOCs; Passive sampling; Sediment pollution |
语种 | 英语 |
scopus关键词 | Biochemistry; Hydrophobicity; Organic chemicals; Organic pollutants; Polychlorinated biphenyls; Polycyclic aromatic hydrocarbons; Risk assessment; Bioavailability; Cfree; HOCs; Passive sampling; Sediment pollution; Sediments; polychlorinated biphenyl; polycyclic aromatic hydrocarbon; polychlorinated biphenyl; polycyclic aromatic hydrocarbon; sea water; baseline conditions; bioavailability; marine sediment; PAH; PCB; porewater; sampling; sediment pollution; spatial distribution; toxicity; Article; bioavailability; concentration (parameters); desorption; Germany; hydrophobicity; mass fragmentography; pollution monitoring; sediment; sensitivity analysis; solid phase microextraction; temperature sensitivity; Wadden Sea; analysis; chemistry; environmental monitoring; North Sea; sediment; water pollutant; water pollution; Atlantic Ocean; German Bight; North Sea; Wadden Sea; Environmental Monitoring; Geologic Sediments; North Sea; Polychlorinated Biphenyls; Polycyclic Aromatic Hydrocarbons; Seawater; Solid Phase Microextraction; Water Pollutants, Chemical; Water Pollution, Chemical |
来源期刊 | Marine Pollution Bulletin
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文献类型 | 期刊论文 |
条目标识符 | http://gcip.llas.ac.cn/handle/2XKMVOVA/150200 |
作者单位 | Hamburg University of Applied Sciences, Department Engineering, Ulmenliet 20, Hamburg, 21033, Germany; Federal Maritime and Hydrographic Agency, Department Marine Science, Wüstland 2, Hamburg, 22589, Germany |
推荐引用方式 GB/T 7714 | Niehus N.C.,Brockmeyer B.,Witt G.. Bioavailability and distribution of PAHs and PCBs in the sediment pore water of the German Bight and Wadden Sea[J],2019,138. |
APA | Niehus N.C.,Brockmeyer B.,&Witt G..(2019).Bioavailability and distribution of PAHs and PCBs in the sediment pore water of the German Bight and Wadden Sea.Marine Pollution Bulletin,138. |
MLA | Niehus N.C.,et al."Bioavailability and distribution of PAHs and PCBs in the sediment pore water of the German Bight and Wadden Sea".Marine Pollution Bulletin 138(2019). |
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