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DOI10.1016/j.marpolbul.2020.110899
Phthalic acid esters – A grave ecological hazard in Cochin estuary; India
Ramzi A.; Gireeshkumar T.R.; Habeeb Rahman K.; Balachandran K.K.; Shameem K.; Chacko J.; Chandramohanakumar N.
发表日期2020
ISSN0025326X
卷号152
英文摘要Distribution and ecological risks of Phthalic acid esters (PAEs) are poorly studied in estuarine environments in India. An attempt is made to chart the sources and assess the ecological risk of six PAE congeners (∑6PAEs), present in dissolved and particulate forms in a tropical ecosystem (Cochin Estuary, India). Terrestrial input, as attested by a clear seasonality with substantial enrichment during monsoon (2–28 μg/L and 31–1203 μg/g; dissolved and particulate PAEs respectively) and post-monsoon (1–7 μg/L and 7–321 μg/g; dissolved and particulate PAEs respectively), was identified as the primary source. DnBP (di-n-butyl phthalate) and DEHP (diethylhexyl phthalate) were found to be the dominant species except for dissolved PAEs at pre-monsoon season. Statistical analysis identified two major clusters, in the ∑6PAEs, composed of medium to high molecular weight PAEs (derived from plastic products) and low molecular weight PAEs (derived from cosmetic products). Calculated Risk Quotient (RQ) indicated values indicated moderate to high ecological risk for DnBP and DEHP congeners is a grim pointer to their detrimental effects on human health through consumption of contaminated organisms. Although substantial enrichment of suspended matter gets flushed out of the estuary during monsoon, there is a net PAE accumulation in the estuary during post-monsoon following an increased sedimentary restitution. Data of PAEs generated herein raises a challenge for immediate enactment of statutory legislation to curb and regulate hazardous contamination of estuaries by phthalic acid esters. © 2020 Elsevier Ltd
英文关键词Ecological risk; Endocrine disruptors; Estuarine water; Phthalic acid esters
语种英语
scopus关键词Atmospheric thermodynamics; Carboxylic acids; Dissolution; Esters; Hazards; Health risks; Molecular weight; Plastic products; Plasticizers; Risk assessment; Water pollution; Di-ethyl-hexyl phthalate; Ecological risks; Endocrine disruptor; Estuarine environments; Estuarine waters; Hazardous contaminations; High molecular weight; Phthalic acid esters; Estuaries; phthalic acid bis(2 ethylhexyl) ester; phthalic acid ester; ester; phthalic acid; phthalic acid derivative; phthalic acid dibutyl ester; bioaccumulation; endocrine disruptor; enrichment; estuarine ecosystem; hazard assessment; seasonality; statistical analysis; alga; Article; Crustacea; ecotoxicity; environmental enrichment; estuary; fish; hazard assessment; health hazard; India; molecular weight; monsoon climate; nonhuman; particulate matter; sea pollution; seasonal variation; water contamination; China; ecosystem; estuary; human; Cochin Estuary; India; Kerala; China; Dibutyl Phthalate; Ecosystem; Esters; Estuaries; Humans; India; Phthalic Acids
来源期刊Marine Pollution Bulletin
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/149179
作者单位Inter University Centre for Development of Marine Biotechnology, School of Marine Sciences, Cochin University of Science and Technology, Kochi, 682016, India; CSIR-National Institute of Oceanography, Regional Centre-Kochi682018, India; Department of Chemical Oceanography, School of Marine Sciences, Cochin University of Science and Technology, Kochi, 682016, India
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Ramzi A.,Gireeshkumar T.R.,Habeeb Rahman K.,等. Phthalic acid esters – A grave ecological hazard in Cochin estuary; India[J],2020,152.
APA Ramzi A..,Gireeshkumar T.R..,Habeeb Rahman K..,Balachandran K.K..,Shameem K..,...&Chandramohanakumar N..(2020).Phthalic acid esters – A grave ecological hazard in Cochin estuary; India.Marine Pollution Bulletin,152.
MLA Ramzi A.,et al."Phthalic acid esters – A grave ecological hazard in Cochin estuary; India".Marine Pollution Bulletin 152(2020).
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