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DOI10.1016/j.atmosres.2019.104740
The characteristics of inorganic gases and volatile organic compounds at a remote site in the Tibetan Plateau
Zhao R.; Dou X.; Zhang N.; Zhao X.; Yang W.; Han B.; Yu H.; Azzi M.; Wang Y.; Bai Z.
发表日期2020
ISSN0169-8095
卷号234
英文摘要In order to study the characteristics of pollutants in the remote background site of Tibetan Plateau, volatile organic compounds (VOCs), NO, NO2, SO2, CO, O3 and meteorological parameters (temperature, relative humidity, rainfall, horizontal wind speed and direction) were measured in the autumn of 2013 at Menyuan station (37.59°N, 101.29°E, 3250 m a.s.l.), which is a newly established background site located in the Tibetan Plateau. The significantly lower average concentrations of NO, NO2, SO2 and CO were observed, indicating the distinct background characteristics at Menyuan. The O3 diurnal variation pattern and correlation analyses revealed the influence of in situ photochemical reactions and vertical mixing during the daytime and the long-range and vertically downslope transport from the upper troposphere or lower stratosphere during the nighttime. A total of 30 VOCs samples were collected and 66 VOCs species were analyzed. The oxygenated VOCs (OVOCs) were the most abundant components and high levels of acetone, acetaldehyde, nonanal, hexachloro-1,3-butadiene, 1,2-dichloroethane and CCl4 were observed. The LOH and OFP analysis confirmed that OVOCs and aromatics were the most active substances, and the VOCs had relatively stable chemical compositions and low photochemical potential. The long-range transport air masses from the southeast of Menyuan station passed by some polluted areas, such as Xining, and could result in the elevated NOx, CO and SO2 concentrations at Menyuan. Therefore, this work enriches the understanding of O3 cycles and transport influence in the Tibetan Plateau. © 2019
英文关键词Background site; Ozone; Photochemical reactivity; Tibetan Plateau; VOCs
学科领域Acetone; Chemical analysis; Nitrogen oxides; Ozone; Photochemical reactions; Volatile organic compounds; Wind; 1 ,2-dichloroethanes; Background site; Chemical compositions; Correlation analysis; Long range transport; Meteorological parameters; Photochemical reactivity; Tibetan Plateau; Chlorine compounds; atmospheric pollution; concentration (composition); diurnal variation; gas; ozone; photochemistry; vertical mixing; volatile organic compound; China; Qinghai-Xizang Plateau
语种英语
scopus关键词Acetone; Chemical analysis; Nitrogen oxides; Ozone; Photochemical reactions; Volatile organic compounds; Wind; 1 ,2-dichloroethanes; Background site; Chemical compositions; Correlation analysis; Long range transport; Meteorological parameters; Photochemical reactivity; Tibetan Plateau; Chlorine compounds; atmospheric pollution; concentration (composition); diurnal variation; gas; ozone; photochemistry; vertical mixing; volatile organic compound; China; Qinghai-Xizang Plateau
来源期刊Atmospheric Research
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/120537
作者单位State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing, 100012, China; Qinghai Environmental Monitoring Center, Xining, 810007, China; CSIRO Energy, 10 Murray Dwyer Circuit, Mayfield WestNSW 2304, Australia; CSIRO, 11 Julius Avenue, North Ryde, NSW 2113, Australia; Key Laboratory for Atmospheric Chemistry, Institute of Atmospheric Composition, Chinese Academy of Meteorological Sciences, Beijing, 100081, China
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GB/T 7714
Zhao R.,Dou X.,Zhang N.,et al. The characteristics of inorganic gases and volatile organic compounds at a remote site in the Tibetan Plateau[J],2020,234.
APA Zhao R..,Dou X..,Zhang N..,Zhao X..,Yang W..,...&Bai Z..(2020).The characteristics of inorganic gases and volatile organic compounds at a remote site in the Tibetan Plateau.Atmospheric Research,234.
MLA Zhao R.,et al."The characteristics of inorganic gases and volatile organic compounds at a remote site in the Tibetan Plateau".Atmospheric Research 234(2020).
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