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DOI10.1016/j.jenvman.2019.06.088
A facile polymerisation of magnetic coal to enhanced phosphate removal from solution
Kajjumba, George William1; Yildirim, Eren2; Aydin, Serdar3; Emik, Serkan2; Agun, Tuba3; Osra, Faisal4; Wasswa, Joseph5
发表日期2019
ISSN0301-4797
EISSN1095-8630
卷号247页码:356-362
英文摘要

Globally, there are increased threats to available freshwater resources due to pollution, climate change, and increased demand from population growth. Phosphorus is one of the essential nutrients required for animal and plant growth. However, when it is released into freshwater resources in excess amounts, it can become a pollutant through eutrophication. This study aimed to enhance the removal of phosphate from water using modified coal. The coal was magnetised by in-situ synthesis using a precipitation technique. To obtain functional groups and mechanical stability, magnetised coal particles were coated with polyaniline, via the polymerisation of aniline to form Magnetised Unburnt Coal Polyaniline (MUC-PANI). The properties of MUC-PANI were investigated using TGA, BET, XRD, Raman spectroscopy, SEM, and FTIR. TGA reviewed MUC-PANI as 58% magnetised coal and 42% polyaniline, while the specific surface area increased from 30.0 to 42.2 m(2)/g after modification. SEM indicated a cauliflower structure on the surface of MUC-PANI due to the successful polymerisation of polyaniline. The FTIR spectrum showed successful adsorption of phosphate due to the formation of incipient peak at1008 cm(-1). The adsorption kinetic data are better fitted to the Elovich model. The Langmuir adsorption capacity of MUC-PANI is 147.1 mg PO43-/g at 25 degrees C and pH 5.0 (initial concentration 10-200 mg/L, dose 0.8 g/L). MUC-PANI is a cost-efficient compound for removal of phosphate because it is made from readily available coal.


WOS研究方向Environmental Sciences & Ecology
来源期刊JOURNAL OF ENVIRONMENTAL MANAGEMENT
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/103138
作者单位1.Univ Nevada, Dept Civil & Environm Engn, Reno, NV 89557 USA;
2.Istanbul Univ Cerrahpasa, Dept Chem Engn, Istanbul, Turkey;
3.Istanbul Univ Cerrahpasa, Dept Environm Engn, Istanbul, Turkey;
4.Umm Al Qura Univ, Dept Civil Engn, Mecca, Saudi Arabia;
5.SUNY Syracuse, Dept Civil & Environm Engn, Syracuse, NY USA
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Kajjumba, George William,Yildirim, Eren,Aydin, Serdar,et al. A facile polymerisation of magnetic coal to enhanced phosphate removal from solution[J],2019,247:356-362.
APA Kajjumba, George William.,Yildirim, Eren.,Aydin, Serdar.,Emik, Serkan.,Agun, Tuba.,...&Wasswa, Joseph.(2019).A facile polymerisation of magnetic coal to enhanced phosphate removal from solution.JOURNAL OF ENVIRONMENTAL MANAGEMENT,247,356-362.
MLA Kajjumba, George William,et al."A facile polymerisation of magnetic coal to enhanced phosphate removal from solution".JOURNAL OF ENVIRONMENTAL MANAGEMENT 247(2019):356-362.
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