CCPortal
DOI10.1039/c9cy01234f
Developmental trends in CO2 methanation using various catalysts
Sreedhar, I.1; Varun, Yaddanapudi1; Singh, Satyapaul A.1; Venugopal, A.2; Reddy, Benjaram M.2
发表日期2019
ISSN2044-4753
EISSN2044-4761
卷号9期号:17页码:4478-4504
英文摘要

Global warming has been a serious concern worldwide. Greenhouse gases like CO2 majorly contribute to the rise in average global temperature. Attempts have been made to reduce the CO2 in the atmosphere. However, carbon capture alone was not found to be commercially viable. Various other green and cost-effective methods to convert CO2 into more useful products have been researched. CO2 methanation was found to be one such vital reaction of converting CO2 to useful fuel, like methane, using different catalysts. In this paper, this vital reaction has been reviewed comprehensively. Studies conducted with respect to materials that have proven catalysts such as Ni, synthesised by impregnation, to be the most suitable, where use of promotors (like Si and Ce) and supports (like zeolites, ceria and MOFs), high pressures, low humidity and optimum temperatures have led to increased selectivity, have been presented. The different reactors/contactors that have been used in this process at various scales, their design parameters, process conditions, performance, and limitations have been discussed which have shown the use of annular fixed bed reactors to be the most favourable. The different mechanisms proposed for the reaction, involving various intermediates, mainly carbenes and formates, and problems incurred in low temperature operation and finding of an appropriate support and promotor have been presented. Thermo-kinetic modelling studies on this reaction have also been presented and discussed. Every section has been summarized in the form of a table. The recent advances as well as future challenges and prospects of the above-said aspects of CO2 methanation have also been cited. Recent advances suggest methods of electrocatalytic reduction potentially employing Cu based compounds and perovskite oxides as catalysts, bio-electrocatalytic reduction using microbes as catalysts, and photocatalytic reduction using noble or critical metals including Ni and TiO2 as catalysts and graphene as a support, for the conversion of carbon dioxide to methane.


WOS研究方向Chemistry
来源期刊CATALYSIS SCIENCE & TECHNOLOGY
文献类型期刊论文
条目标识符http://gcip.llas.ac.cn/handle/2XKMVOVA/102787
作者单位1.BITS Pilani Hyderabad Campus, Dept Chem Engn, Hyderabad 500078, Telangana, India;
2.IICT Tarnaka, I&PC Div, Hyderabad 500007, Telangana, India
推荐引用方式
GB/T 7714
Sreedhar, I.,Varun, Yaddanapudi,Singh, Satyapaul A.,et al. Developmental trends in CO2 methanation using various catalysts[J],2019,9(17):4478-4504.
APA Sreedhar, I.,Varun, Yaddanapudi,Singh, Satyapaul A.,Venugopal, A.,&Reddy, Benjaram M..(2019).Developmental trends in CO2 methanation using various catalysts.CATALYSIS SCIENCE & TECHNOLOGY,9(17),4478-4504.
MLA Sreedhar, I.,et al."Developmental trends in CO2 methanation using various catalysts".CATALYSIS SCIENCE & TECHNOLOGY 9.17(2019):4478-4504.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Sreedhar, I.]的文章
[Varun, Yaddanapudi]的文章
[Singh, Satyapaul A.]的文章
百度学术
百度学术中相似的文章
[Sreedhar, I.]的文章
[Varun, Yaddanapudi]的文章
[Singh, Satyapaul A.]的文章
必应学术
必应学术中相似的文章
[Sreedhar, I.]的文章
[Varun, Yaddanapudi]的文章
[Singh, Satyapaul A.]的文章
相关权益政策
暂无数据
收藏/分享

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。